The cemented backfill (CB) utilizing coal gangue (CG) and fly ash (FA) is widely applied in coal mines. However, the bleeding and shrinkage of CB leads to insufficient contact with surrounding rock, which is not beneficial for controlling roof subsidence and even stope stability. Herein, a cemented foam backfill (CFB) formulation is demonstrated, employing hydrogen dioxide (H₂O₂) as a chemical foaming agent. The cement and FA show noticeable inhibiting effects on volume expansion due to the network formed by their hydrates. Moderately lower cement, FA, and solid concentration are beneficial to improve volume increment and prolong expanding duration. A foaming coefficient (k) is proposed in theory to evaluate the foaming efficiency. The k_em values, determined by volume evolution experiments of CFB slurries, provide a calculation basis for the needed dosage of H₂O₂ solution targeting specific volume increment. CFB specimens with expanding ratios of 21%~103% and densities of 994~592 kg/cm³ were prepared, with an actual foaming coefficient of 52.40 cm³/g and uniaxial compressive strength (UCS) of 0.32~0.55 MPa. The mass of H₂O₂ solution was 1.9%~11.3% of cement and 0.29%~1.67% of total solid materials by weight. The UCS decline compared to CB was attributed to rich pores observed by CT and carbonation indicated by X-ray diffraction (XRD).

The hydration products and strength of cement pastes incorporated with ground blast furnace slag (GBFS) (0% and 20% replacement) have been investigated under steam curing condition (80 °C for 7 h and 7 d) in comparison with normal curing condition (moist curing for 28 d). The results show that, during the initial 80 °C steam curing for 7 h, in addition to the filler effect, GBFS is still involved in cement hydration. The abundant available Al phase and Mg phase in GBFS promote the formation of flake-like hydrotalcite, foil-like C-(A)-S-H gels, as well as equant grain-shaped C-(A)-S-H gels. Prolonging the steam curing time to 7 d further improves the formation of hydrogarnet. Since the formation of both hydrogarnet and hydrotalcite can consume the available Al, steam curing for 7 d seems to favor the formation of low Al C-(A)-S-H gels. In addition, due to the formation of a large amount of hydration products, the influence of 20% GBFS addition on the demolding strength of initial steam-cured cement mortar (80 °C for 7 h) is almost negligible. However, further extending the steam curing time to 7 d increases the strength gap between 20% GBFS blended cement mortar and pure cement mortar, and the related mechanism is discussed.

Research focusing on waste management and CO₂ mineralization simultaneously has been a popular topic in the mining community, and a common approach is to mineralize CO₂ with coal-based solid waste (CSW, e.g., gangue (CG), fly ash (FA), coal gasification slag (CGS)) produced by mining activities. Despite the understanding of CO₂ mineralization by cementitious materials, the mineralization capacity of alkali-activated CSWs remains unknown. Therefore, the mineral composition evolution and mineralization capacity of different alkali-activated materials (prepared with CG, FA, CGS, and sodium hydroxide (which works as the alkali-activator), respectively) are investigated with the adoption of Gibbs Energy Minimization Software (GEMS). The results indicate that the abovementioned three alkali-activated CSWs are majorly composed of calcium silicate hydrate, magnesium silicate hydrate, kaolinite, sodium zeolite, and liquid. Due to the difference in the chemical composition of different CSWs, the amount of hydration products varies. Specifically, the alkali-activated CSWs made with CGS have the maximum calcium silicate hydrate (C-S-H), while those prepared with FA enjoy the lowest porosity. In addition, the CO₂ mineralization process will result in the formulation of carbonate and, theoretically, the maximum quantity of mineralized CO₂ is less than 20% of the binder used. Furthermore, compared with CG and CGS, FA is characterized with the highest mineralization capacity. The findings in this study contribute to the understanding of CO₂ mineralization with alkali-activated CSWs.