Coal gangue-based geopolymer (CGGP) is one of the hot spots existing in the recycling of coal gangue resources due to its good comprehensive mechanical properties. However, the coal gangue structure is stable and reactivity is poor, so the coal gangue needs to be activated before utilization. In this paper, the microstructure changes of activated coal gangue by different mechanical and thermal activation methods, as well as the mechanical properties and microstructure changes of the CGGP specimens were studied by experimental investigation. The results indicated that mechanical activation and thermal activation were two effective methods to change the reactivity of coal gangue, which consisted of destroying the stable kaolinite structure and improving the activity of coal gangue. Conversely, part of the amorphous structure in coal gangue was destroyed when the activation temperature reached 900 °C, which was not conducive to the further enhancement of coal gangue activity. For the CGGP prepared by thermally activated coal gangue and modified sodium silicate alkali solution, the uniaxial compressive strength of the CGGP specimens decreased with thermal activation temperatures of the raw coal gangue materials at 700 °C, 800 °C, and 900 °C. The main reason for this was the lower amount of the active metakaolin structure in coal gangue at 900 °C, which was not conducive to the geopolymerization process.

China’s total coal production in 2021 exceeded 4.13 billion tons, 52% of the world’s total. Coal gangue, a solid waste of coal mining accounts for 15–20% of coal production, when directly discharged on the ground surface as waste heaps, it occupies large areas of land and cause environmental pollution. This paper summarizes the existing gangue backfilling methods, their working principles, efficiency, and application status. The methods that are meeting Middle and Western China’s mining demands are discussed in detail. The state-of-the-art technologies that can realize high-efficiency, centralized, and large-scale underground backfilling of coal gangue are analyzed. This paper shows that the industrial implementation of these technologies can increase the current maximum disposal capacity of coal gangue by three times, reaching five million tons per year. The equipment innovation and automation are analyzed, and the environmental effect of coal gangue backfilling is discussed. This review offers inspirations and guidelines for coal gangue disposal and the environmental hazard reduction of coal mining.

Solid backfill coal mining technology has been widely applied in coal seams that are at risk of hard roof. Using actual measured strain–stress curves of the backfill body and the similarity theory, this study designed and employed four experimental models for physical simulation, corresponding to roof-controlled backfilling ratios of 0%, 40%, 82.5% and 97% using the geological conditions of Face No. 6304 in the Jining No. 3 coal mine—a solid backfill coal mining face under a hard roof. A non-contact strain measurement system and pressure sensors were used to monitor the deformation of the overlying strata and changes in abutment stress ahead of the face during mining of the models for varying roof-controlled backfilling ratios. The results indicated that the solid backfill body was able to support the roof. As the roof-controlled backfilling ratio was increased, the maximum subsidence of the roof and the maximum height of the cracks decreased. When the roof-controlled backfilling ratio was 82.5% or higher, the working face did not display any obvious initial fractures or periodic fractures, and both the value and the impact range of the abutment stress ahead of the face decreased.

Uranium mining waste causes serious radiation-related health and environmental problems. This has encouraged efforts toward U(VI) removal with low cost and high efficiency. Typical uranium adsorbents, such as polymers, geopolymers, zeolites, and MOFs, and their associated high costs limit their practical applications. In this regard, this work found that the natural combusted coal gangue (CCG) could be a potential precursor of cheap sorbents to eliminate U(VI). The removal efficiency was modulated by chemical activation under acid and alkaline conditions, obtaining HCG (CCG activated with HCl) and KCG (CCG activated with KOH), respectively. The detailed structural analysis uncovered that those natural mineral substances, including quartz and kaolinite, were the main components in CCG and HCG. One of the key findings was that kalsilite formed in KCG under a mild synthetic condition can conspicuous enhance the affinity towards U(VI). The best equilibrium adsorption capacity with KCG was observed to be 140 mg/g under pH 6 within 120 min, following a pseudo-second-order kinetic model. To understand the improved adsorption performance, an adsorption mechanism was proposed by evaluating the pH of uranyl solutions, adsorbent dosage, as well as contact time. Combining with the structural analysis, this revealed that the uranyl adsorption process was mainly governed by chemisorption. This study gave rise to a utilization approach for CCG to obtain cost-effective adsorbents and paved a novel way towards eliminating uranium by a waste control by waste strategy.