The corrosion behavior of 2A02 Al alloy under 4 mg/cm² NaCl deposition at different temperatures (from 30 to 80 °C) has been studied. This corrosion behavior was researched using mass-gain, scanning electron microscopy-SEM, laser scanning confocal microscopy-LSCM, X-ray photoelectron spectroscopy-XPS and other techniques. The results showed and revealed that the corrosion was maximal at 60 °C after 200 h of exposure. The increase of temperature not only affected the solubility of oxygen gas in the thin film, but also promoted the transport of ions (such as Cl⁻), and the formation of protective AlO(OH), which further affects the corrosion speed.

The corrosion behavior of pure Ti under a solid NaCl deposit in a wet O₂ flow at 600 °C has been studied. The results showed that the corrosion rate was greatly accelerated by solid NaCl, which destroyed the compact and protective TiO₂ scale to yield non-protective N₄Ti₅O₁₂ and other products. Detailed scanning electron microscopy (SEM) equipped with an energy dispersive spectrometer (EDX), and X-ray diffraction (XRD) analysis showed that, during the corrosion process, the metal (Ti) diffused outward rapidly and reacted with the wet O₂ to form a thick and porous corrosion products scale. The electrochemical reaction was also observed during the whole corrosion process at 600 °C, which further accelerated the corrosion rate. A possible mechanism has been proposed for pure Ti covered with a solid NaCl deposit in wet O₂ at 600 °C, based on the experimental results.

In this paper, the corrosion behavior of GH4169 superalloy under alternating oxidation (at 900 °C) and solution immersion (in 3.5% NaCl solution, 30 ± 1 °C) has been studied by SEM, XRD, XPS, and electron probe microanalysis (EPMA). The results show that the alternating environment increases the corrosion rate of GH4169. The reaction of NaCl and Cr₂O₃ generates various volatile and soluble corrosion products, such as Na₂Cr₂O₇, CrCl₃, Cl₂, and Na₂CrO₄, at a high temperature. The destruction of the protective Cr₂O₃ film leads to the increase of defects in the oxide scale, promoting the formation of oxides, such as NiO and Fe₂O₃, and changes the composition and structure of the oxide film. After repeated iterations, the mixed oxides will result in the spalling of the oxide film because they can reduce the fracture toughness of the corrosion scale. Therefore, the corrosion is comprehensively intensified.