The capillary absorption capacity exerts an important effect on the durability of cement-based materials and is closely related to the pore structure. In this study, a variety of cement-based specimens were examined. The capillary water absorption and pore structure of the samples were determined using a gravimetric method and mercury intrusion porosimetry (MIP), respectively. The capillary water absorption coefficients for different water–binder ratios, diverse types and dosages of mineral admixtures, and various preloads were measured. The experimental results were analyzed and compared with data available in the current literature. The test results showed that the capillary water absorption performance of cement-based materials increased with an increasing water–binder ratio, first decreased and then increased with an increasing fly ash dosage, decreased with an increasing mineral power dosage, and decreased when the preload was less than a critical value and increased rapidly when the preload was greater than the critical value. The relationship between the capillary absorption coefficient and porosity was nearly linear. Water absorption by cement-based materials mainly correlated with pore diameters in the range of 10~1000 nm. The capillary water absorption coefficient increased continuously with the increase of pore fractal dimension.

For the sustainable development of construction materials, supplementary cementitious materials (SCMs) are commonly added to self-compacting concrete (SCC). This paper reviewed the application techniques and hydration mechanisms of SCMs in SCC. The impacts of SCMs on the microstructure and performance of SCC were also discussed. SCMs are used as a powder material to produce SCC by replacing 10% to 50% of cement. Hydration mechanisms include the pozzolanic reaction, alkaline activation, and adsorption effect. Moreover, the filling effect and dilution effect of some SCMs can refine the pore structure and decrease the temperature rise of concrete, respectively. Specifically, the spherical particles of fly ash can improve the fluidity of SCC, and the aluminum-containing mineral phase can enhance the resistance to chloride ion penetration. Silica fume will increase the water demand of the paste and promote its strength development (a replacement of 10% results in a 20% increase at 28 days). Ground-granulated blast furnace slag may reduce the early strength of SCC. The adsorption of Ca²⁺ by CaCO₃ in limestone powder can accelerate the hydration of cement and promote its strength development.