A metal–ceramic composite target for magnetron sputtering was fabricated for the first time by a robotic complex for the detonation spraying of coatings equipped with a multi-chamber detonation accelerator. A mixture of metal and ceramic NiCr/B4C powders was sprayed onto the copper base of the cylindrical composite target cathode. The study of the structure of a metal–ceramic composite coating target using scanning electron microscopy showed that the coating material is dense without visible pores; the elemental composition is evenly distributed in the material. The study of the cathode sputtering area after deposition in the DC mode showed that there are uniform traces of annular erosion on the target surface. The obtained cathode target with an NiCr-70B4C coating was used to deposit the NiB-Cr7C3 coating on flat specimens of 65G steel using equipment for magnetron sputtering UNICOAT 200. The coating was applied in the Direct Current mode. A dense NiB-Cr7C3 coating with a thickness of 2 μm was obtained. The NiB-Cr7C3 coating has a quasi-amorphous structure. The microstructures and concentration of oxygen and carbon impurities throughout the entire thickness of the coating were investigated by means of transmission electron microscopy. The results of the study show that the coatings have a nanocrystalline multi-phase structure. The microhardness of the NiB-Cr7C3 coating reached 10 GPa, and the adhesion fracture load exceeded 16 N. The results will open up new prospects for the further elaboration of technology for obtaining original composite cathodes for magnetron sputtering using detonation spraying of coatings.
TiN films synthesized on leucosapphire substrates by dual magnetron sputtering have been annealed in vacuum at 600, 700, 800, and 900°C for 2 min. The microstructure and morphology of the films have...
Zinc-oxide films 1.4 μm in thickness are deposited onto glassy substrates by the dual magnetron-assisted sputtering of zinc targets in an argon and oxygen gas atmosphere. The dependences of...
The durability of the cutting edge in a centrifugal beet shredder affects the quality of the beet chips and the overall productivity. Its performance may b
16 October 2024 in Construction Materials and Products
Aluminum oxide (Al2O3) remains a crucial material in the field of engineering ceramics, particularly in industrial applications. Notably, its transitional phases, in addition to the α-phase, demonstrate good properties. In this article the structure and properties of coatings obtained by detonation spraying from aluminum oxide powder with different production methods (fragmentation and spherical particle shape) and crystalline modification (α-Al2O3 and γ-Al2O3) but with similar average particle size were studied. The goal of the study was to investigate the influence of the morphology and phase composition of the powder on such properties of the coatings as microstructure, porosity, roughness and hardness. The results of the study showed that agglomerated spherical powder leads to low porosity of the coatings, while crushed fragmentation particles provide dense layers. In addition, the coating obtained using fragmentation powder showed higher hardness, and the surface had twice the roughness, compared to the coating applied using spheroidal powder. These results confirm the effect of the morphology of the original powder on the final properties and efficiency of the coatings. The study showed that the detonation spraying method allows for the efficient application of coatings from two types of Al2O3 powders with different morphology (spherical and fragmentation) and phase composition (γ-Al2O3and α-Al2O3) but with similar particle sizes.