Noble metal NPs are highly attractive candidates because of their unique combination of physical, chemical, mechanical, and structural properties. A lot of developments in this area are still fascinating the materials research community, and are broadly categorized in various sectors such as chemical sensors, biosensors, Förster resonance energy transfer (FRET), and microelectronic applications. The related function and properties of the noble metals in these areas can be further tailored by tuning their chemical, optical, and electronic properties that are influenced by their size, shape, and distribution. The most widely used Au and Ag NPs in dispersed phase below 100 nm exhibit strong color change in the visible range which alters upon aggregation of the NPs. The chemical sensing of the analyte is influenced by these NPs aggregates. In this article, we have summarized the uniqueness of noble metal NPs, their synthesis methods, nucleation and growth process, and their important applications in chemical sensing, microelectronic packaging, and Förster resonance energy transfer.
4 January 2024 in Journal of Materials Research and Technology
In this paper, the effect of scan rate on the corrosion parameters and electrochemical behaviour of Retrogression and Re-aging (RRA) heat treatment of 7075 aluminium alloy has been investigated by Potentiodynamic polarization (PD) and electrochemical impedance spectroscopy (EIS) methods. The Potentiodynamic polarization (PD) curves were obtained at various scan rates for aged aluminium alloys in 0.5 M H2SO4 solution. The results show that at high scan rates shows unpredicted fluctuation of charging current, whereas at lower scan rates fewer disturbances are observed. The aged samples were chemically and mechanically characterized. It was observed that the RRA at 0.7 h shown improved corrosion property as well as mechanical properties compared to T6 temper. The corrosion properties were confirmed by EIS and polarization experiments.
In this study, we have investigated the electrochemical corrosion behavior of boron carbide (B4C) ceramic-reinforced Al-Mg-Si matrix composites in various aqueous environments (NaOH, NaCl, HCl, and H2SO4). The samples were produced by the powder metallurgy (P/M) route and the corrosion investigations were conducted by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) methods. The morphology of the as-prepared and corroded samples was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) studies. The investigations revealed that the corrosion resistance of Al-Mg-Si composites is highest in NaCl medium due to a less negative corrosion potential, higher charge transfer (Rct) resistance, and lower double-layer capacitance (Cdl) as compared to other media. The SEM morphology suggests that B4C ceramics enhance corrosion resistance by forming a protective barrier layer of OH- and Cl- deposits in the composite and unreinforced alloy, respectively.