Section Engineering Systems and Services, Faculty of Technology, Policy, and Management, Delft University of Technology, 2628 BX Delft, the Netherlands
Dr. Georgios Archimidis Tsalidis
Section Engineering Systems and Services, Faculty of Technology, Policy, and Management, Delft University of Technology, 2628 BX Delft, the Netherlands
Power generation from biomass is mentioned as a means to make our society more sustainable as it decreases greenhouse gas emissions of fossil origin and reduces the dependency on finite energy carriers, such as coal, oil and natural gas. When assessing the sustainability of power generation from biomass, it is important to consider the supply chain of the used biofuel by conducting a life cycle assessment of the system. Besides regular sustainability assessments, such as the calculation of the environmental sustainability, attention should be paid to exergy losses, i.e. the loss of 'energy quality', caused by the system as a whole, because every process and activity is accompanied with the loss of exergy and because the amount of exergy on earth can only be replenished by capturing new exergy from solar and tidal energy. This research compares the use of livestock manure and verge grass for power generation by assessing the systems from an environmental as well as an exergetic life cycle point of view. The assessed systems are the following: combustion of bioethanol from the fermentation of verge grass, combustion of substitute natural gas from anaerobic digestion of cow and pig manure and combustion of substitute natural gas from supercritical water gasification of cow and pig manure. The environmental sustainability is assessed by calculating ReCiPe endpoint indicators and the exergetic sustainability is assessed by applying the relatively new Total Cumulative Exergy Loss (TCExL) method. The TCExL method considers all exergy losses caused by a technological system during its life cycle, i.e. the internal exergy loss caused by the conversion of materials and energy, the abatement of emissions and the exergy loss related to land use. In addition to comparing the three systems as well as both assessment methods, the influence of taking into account the system's by-products as 'avoided products' and via 'allocation' on the assessment results is investigated. The bioethanol system appears more sustainable from an environmental sustainability point of view, while the bioethanol and supercritical water gasification systems are preferred from an exergetic sustainability point of view. The indicator of the environmental sustainability assessment is highly influenced by the way of taking into account by-products, while the exergetic sustainability indicator is not.
Industrial agriculture results in environmental burdens due to the overuse of fertilizers and pesticides. Fungicides is a class of pesticides whose application contributes (among others) to human toxicity and ecotoxicity. The European Union aims to increase organic agriculture. For this reason, this work aims to analyze climate change, freshwater ecotoxicity, terrestrial ecotoxicity, human toxicity, (terrestrial) acidification, and freshwater eutrophication impacts of fungicides and calculate expected benefits to human health (per European citizen) and ecosystem quality (terrestrial) with life cycle assessment (LCA) during crop production. The Scopus database was searched for LCA studies that considered the application of fungicides to specific crops. The analysis shows how many systemic and contact fungicides were considered by LCA studies and what was the applied dosage. Furthermore, it shows that fungicides highly contribute to freshwater ecotoxicity, terrestrial ecotoxicity, human toxicity, and freshwater eutrophication for fruits and vegetables, but to a low extent compared to all considered environmental impacts in the case of cereals and rapeseed. Expected benefits to human health and ecosystem quality after fungicides elimination are greater for fruits and vegetables, ranging between 0 to 47 min per European citizen in a year and 0 to 90 species per year, respectively.
Torrefaction is a promising biomass upgrading technology as it makes biomass more coal alike and offers benefits in logistics and handling operations. Gasification is an attractive thermochemical conversion technology due to its flexibility in the product gas end-uses. Therefore, it is valuable to investigate whether additional benefits are foreseen when torrefaction is coupled with gasification. Therefore, two commercial torrefied wood fuels and their parent materials are gasified at 800–850 °C under atmospheric steam-oxygen circulating fluidized bed gasification conditions and magnesite as bed material. The torrefied feedstocks consisted of wood residues torrefied by Topell at 250 °C (Topell black), and mixed wood and wood residues torrefied by Torrcoal at 300 °C (Torrcoal black). The gasification results show that torrefaction resulted in an increased gas quality, as it yielded higher H2 and CO contents, a decrease of the CO2 content, increased gas yield and a significant decrease of the total tar content for both feedstocks. For the Torrcoal samples, torrefaction resulted in a decrease in the carbon conversion efficiency (CCE). In addition, the cold gas efficiency (CGE) remained approximately the same due to the increase in the H2 and CO contents. The Topell samples showed an increase in the CCE and CGE upon torrefaction, but this could be attributed to a significant grinding in the screw feeder. It is generally concluded that both torrefied fuels may offer benefits as a feedstock for steam-oxygen blown circulating fluidized bed gasification, in particular in terms of gas quality and yield.