Waveform decomposition is needed as a first step in the extraction of various types of geometric and spectral information from hyperspectral full-waveform LiDAR echoes. We present a new approach to deal with the ”Pseudo-monopulse” waveform formed by the overlapped waveforms from multi-targets when they are very close. We use one single skew-normal distribution (SND) model to fit waveforms of all spectral channels first and count the geometric center position distribution of the echoes to decide whether it contains multi-targets. The geometric center position distribution of the ”Pseudo-monopulse” presents aggregation and asymmetry with the change of wavelength, while such an asymmetric phenomenon cannot be found from the echoes of the single target. Both theoretical and experimental data verify the point. Based on such observation, we further propose a hyperspectral waveform decomposition method utilizing the SND mixture model with: 1) initializing new waveform component parameters and their ranges based on the distinction of the three characteristics (geometric center position, pulse width, and skew-coefficient) between the echo and fitted SND waveform and 2) conducting single-channel waveform decomposition for all channels and 3) setting thresholds to find outlier channels based on statistical parameters of all single-channel decomposition results (the standard deviation and the means of geometric center position) and 4) re-conducting single-channel waveform decomposition for these outlier channels. The proposed method significantly improves the range resolution from 60cm to 5cm at most for a 4ns width laser pulse and represents the state-of-the-art in ”Pseudo-monopulse” waveform decomposition.

The 101-channel full-waveform hyperspectral LiDAR (FWHSL) is able to simultaneously obtain geometric and spectral information of the target, and it is widely applied in 3D point cloud terrain generation and classification, vegetation detection, automatic driving, and other fields. Currently, most waveform data processing methods are mainly aimed at single or several wavelengths. Hidden components are revealed mainly through optimization algorithms and comparisons of neighbor distance in different wavelengths. The same target may be misjudged as different ones when dealing with 101 channels. However, using the gain decomposition method with dozens of wavelengths will change the spectral intensity and affect the classification. In this paper, for hundred-channel FWHSL data, we propose a method that can detect and re-decompose the channels with outliers by checking neighbor distances and selecting specific wavelengths to compose a characteristic spectrum by performing PCA and clustering on the decomposition results for object identification. The experimental results show that compared with the conventional single channel waveform decomposition method, the average accuracy is increased by 20.1%, the average relative error of adjacent target distance is reduced from 0.1253 to 0.0037, and the degree of distance dispersion is reduced by 95.36%. The extracted spectrum can effectively characterize and distinguish the target and contains commonly used wavelengths that make up the vegetation index (e.g., 670 nm, 784 nm, etc.).

Graphene quantum dots (GQDs), fascinating semiconductors with stable photoluminescence (PL), have important potential applications in the fields of biology, medicine, and new semiconductor devices. However, it is still challenging to overcome the weak PL intensity. Here, we report a strategy for selective resonance enhancement of GQD fluorescence using gold nanoparticles (AuNPs) as plasmas. Interestingly, the addition of low concentration AuNP makes AuNP/GQDs exhibit significant fluorescence enhancement of 2.67 times in the visible range. The addition of high concentration AuNP leads to the formation of an excitation peak at 421 nm and selectively enhances certain radiation modes. We concluded that the main reason for the selective enhancement of PL intensity in high concentration AuNP is the transfer of generous hot electrons at high energy states from AuNP to GQD and relaxation to the ground state. The electron resonance of low concentration AuNP transfers to GQD and relaxes to lower energy levels, exhibiting an overall enhancement of PL intensity. We apply it for detection of the heavy metal ion Cr³⁺, and verify that it has a correlation coefficient of 97.36%. We believe AuNP/GQDs can be considered excellent candidates for heavy metal detection and high fluorescence bio-imaging.

Despite the wide applications of full-waveform light detection and ranging (FW-LiDAR) on target detection and recognizing, topographical mapping, and ecological management, etc., the mapping between the echo waveform and the properties of the targets, even for typical three-dimensional (3D) targets, has not been established. The mechanics of the modulation of targets on the echo waveform is thus ambiguous, constraining the retrieval of target properties in FW-LiDAR. This paper derived the formula of echo waveform modulated by typical 3D targets, namely, a rectangular prism, a regular hexagonal prism, and a cone. The modulation of shape, size, position, and attitude of 3D targets on the echo waveform has been investigated extensively. The results showed that, for prisms, variations in the echo waveforms under various factors essentially arise from changes in the inclination angles of their reflective surfaces and their positions relative to the laser spot. For cones, their echo waveforms can be approximated and analyzed using isosceles triangular micro-facets. The work in this paper is helpful in probing the modulation of 3D targets on echo waveform, as well as extracting the properties of 3D targets in FW-LiDAR domains, which are significant in areas ranging from topographical mapping to space debris monitoring.