Annually, the olive oil industry generates a significant amount of by-products, such as olive pomace, olive husks, tree prunings, leaves, pits, and branches. Therefore, the recovery of these residues has become a major challenge in Mediterranean countries. The utilization of olive industry residues has received much attention in recent years, especially for energy purposes. Accordingly, this primary experimental study aims at investigating the potential of olive biomass waste for energy recovery in terms of synthesis gas (or syngas) production using the thermal arc plasma gasification method. The olive charcoal made from the exhausted olive solid waste (olive pomace) was chosen as a reference material for primary experiments with known composition from the performed proximate and ultimate analysis. The experiments were carried out at various operational parameters: raw biomass and water vapour flow rates and the plasma generator power. The producer gas involved principally CO, H₂, and CO₂ with the highest concentrations of 41.17%, 13.06%, and 13.48%, respectively. The produced synthesis gas has a lower heating value of 6.09 MJ/nm³ at the H₂O/C ratio of 3.15 and the plasma torch had a power of 52.2 kW.

The depletion and usage of fossil fuels causes environmental issues and alternative fuels and technologies are urgently required. Therefore, thermal arc water vapor plasma for a fast and robust waste/biomass treatment is an alternative to the syngas method. Waste cooking oil (WCO) can be used as an alternative potential feedstock for syngas production. The goal of this experimental study was to conduct experiments gasifying waste cooking oil to syngas. The WCO was characterized in order to examine its properties and composition in the conversion process. The WCO gasification system was quantified in terms of the produced gas concentration, the H₂/CO ratio, the lower heating value (LHV), the carbon conversion efficiency (CCE), the energy conversion efficiency (ECE), the specific energy requirements (SER), and the tar content in the syngas. The best gasification process efficiency was obtained at the gasifying agent-to-feedstock (S/WCO) ratio of 2.33. At this ratio, the highest concentration of hydrogen and carbon monoxide, the H₂/CO ratio, the LHV, the CCE, the ECE, the SER, and the tar content were 47.9%, 22.42%, 2.14, 12.7 MJ/Nm³, 41.3% 85.42%, 196.2 kJ/mol (or 1.8 kWh/kg), and 0.18 g/Nm³, respectively. As a general conclusion, it can be stated that the thermal arc-plasma method used in this study can be effectively used for waste cooking oil gasification to high quality syngas with a rather low content of tars.

This study investigated biomass (wood pellets) gasification to syngas using direct current (DC) thermal arc plasma at atmospheric pressure. Water vapor was used as a main gasifying agent and a plasma-forming gas. The biomass gasification system was quantified in terms of the producer gas composition, the tar content, the H₂/CO ratio, the carbon conversion efficiency, the energy conversion efficiency and the specific energy requirements. It was found that the gasification performance efficiency was highest at the water vapor-to-biomass ratio of 0.97. The producer gas was mostly composed of H₂ (43.86 vol.%) and CO (30.93 vol.%), giving the H₂/CO ratio of 1.42 and the LHV of 10.23 MJ/Nm³. However, high content of tars of 13.81 g/Nm³ was obtained in the syngas. The yield of H₂ and CO was 48.31% and 58.13%, respectively, with the highest producer gas yield of 2.42 Nm³/kg biomass. The carbon conversion efficiency and the energy conversion efficiency were 100% and 48.83%, respectively, and the production of 1 kg of syngas required 1.78 kWh of electric energy input. Finally, the obtained results were compared with different plasma methods, including plasma-assisted application coupled with conventional gasification.