Annually, the olive oil industry generates a significant amount of by-products, such as olive pomace, olive husks, tree prunings, leaves, pits, and branches. Therefore, the recovery of these residues has become a major challenge in Mediterranean countries. The utilization of olive industry residues has received much attention in recent years, especially for energy purposes. Accordingly, this primary experimental study aims at investigating the potential of olive biomass waste for energy recovery in terms of synthesis gas (or syngas) production using the thermal arc plasma gasification method. The olive charcoal made from the exhausted olive solid waste (olive pomace) was chosen as a reference material for primary experiments with known composition from the performed proximate and ultimate analysis. The experiments were carried out at various operational parameters: raw biomass and water vapour flow rates and the plasma generator power. The producer gas involved principally CO, H2, and CO2 with the highest concentrations of 41.17%, 13.06%, and 13.48%, respectively. The produced synthesis gas has a lower heating value of 6.09 MJ/nm3 at the H2O/C ratio of 3.15 and the plasma torch had a power of 52.2 kW.
The depletion and usage of fossil fuels causes environmental issues and alternative fuels and technologies are urgently required. Therefore, thermal arc water vapor plasma for a fast and robust waste/biomass treatment is an alternative to the syngas method. Waste cooking oil (WCO) can be used as an alternative potential feedstock for syngas production. The goal of this experimental study was to conduct experiments gasifying waste cooking oil to syngas. The WCO was characterized in order to examine its properties and composition in the conversion process. The WCO gasification system was quantified in terms of the produced gas concentration, the H2/CO ratio, the lower heating value (LHV), the carbon conversion efficiency (CCE), the energy conversion efficiency (ECE), the specific energy requirements (SER), and the tar content in the syngas. The best gasification process efficiency was obtained at the gasifying agent-to-feedstock (S/WCO) ratio of 2.33. At this ratio, the highest concentration of hydrogen and carbon monoxide, the H2/CO ratio, the LHV, the CCE, the ECE, the SER, and the tar content were 47.9%, 22.42%, 2.14, 12.7 MJ/Nm3, 41.3% 85.42%, 196.2 kJ/mol (or 1.8 kWh/kg), and 0.18 g/Nm3, respectively. As a general conclusion, it can be stated that the thermal arc-plasma method used in this study can be effectively used for waste cooking oil gasification to high quality syngas with a rather low content of tars.
As the industry develops and energy demand increases, wind turbines are increasingly being used to generate electricity, resulting in an increasing number of obsolete turbine blades that need to be properly recycled or used as a secondary raw material in other industries. The authors of this work propose an innovative technology not yet studied in the literature, where the wind turbine blades are mechanically shredded and micrometric fibers are formed from the obtained powder using plasma technologies. As shown by SEM and EDS studies, the powder is composed of irregularly shaped microgranules and the carbon content in the obtained fiber is lower by up to seven times compared with the original powder. Meanwhile, the chromatographic studies show that no hazardous to the environment gases are formed during the fiber production. It is worth mentioning that this fiber formation technology can be one of the additional methods for recycling wind turbine blades, and the obtained fiber can be used as a secondary raw material in the production of catalysts, construction materials, etc.
29 June 2023 in Clean Technologies and Environmental Policy
The global coronavirus (COVID-19) pandemic in early 2020 caused the amount of medical waste, especially plastic waste, to increase. The pandemic exacerbated the plastic waste management problem, including the need to find more sustainable treatment methods. This study investigated the sustainable conversion of plastic waste (FFP2-type face masks) to syngas via pure CO2 plasma gasification to recover energy and reduce environmental pollution. A direct current (DC) thermal arc plasma torch of 40.6–68.4 kW power generated the plasma stream. Carbon dioxide (CO2), as a greenhouse gas (GHG), was used as the main plasma-forming gas and gasifying agent. The 140thermal feedstock input plasma gasification system was used in the study. The effect of the CO2-to-C ratio on the gasification performance efficiency was investigated. The best CO2 plasma gasification process performance was obtained at a CO2-to-C ratio of 2.34. In these conditions, the main syngas components (H2 + CO) comprised 80.46 vol.% (H2: 24.62 vol.% and CO: 55.84 vol.%) and the following values were seen for the heating value of the syngas (LHVsyngas: 13.88 MJ/Nm3), the syngas yield (3.13 Nm3/kgFFP2), the tar content in the syngas (23.0 g/Nm3), the carbon conversion efficiency (CCE: 70.6%), and the cold gas efficiency (CGE: 47.8%). Additionally, the plasma gasification process mass and energy balance were evaluated. It was demonstrated that CO2 plasma gasification could be a promising thermochemical treatment technology for sustainable plastic waste disposal and the simultaneous utilization of greenhouse gases, such as carbon dioxide.