Ni 3 FeN and a N-doped carbon shell have improved electrical conductivity with the electronic structure modified through the extra electrons of nitrogen. Ni 3 FeN@NC in the water splitting reaction provide excellent electrochemical catalytic properties.
Water electrolyzers powered by renewable energy are emerging as clean and sustainable technology for producing hydrogen without carbon emissions. Specifically, anion exchange membrane (AEM) electrolyzers utilizing non‐platinum group metal (non‐PGM) catalysts have garnered attention as a cost‐effective method for hydrogen production, especially when integrated with solar cells. Nonetheless, the progress of such integrated systems is hindered by inadequate water electrolysis efficiency, primarily caused by poor oxygen evolution reaction (OER) electrodes. To address this issue, a NiFeCo─OOH has developed as an OER electrocatalyst and successfully demonstrated its efficacy in an AEM electrolyzer, which is powered by renewable electricity and integrated with a silicon solar cell.
One of the remarkable choices for active smart window technology is adopting a metal active layer via reversible metal electrodeposition (RME). As the metal layer efficiently blocks the solar energy gain, even a hundred-nanometer-thick scale, RME-based smart window has great attention. Recent developments are mainly focused on the various cases of electrolyte components and composition meeting technological standards. As metal nanostructures formed through the RME process involve plasmonic phenomena, advanced analysis, including plasmonic optics, which is beyond Beer–Lambert’s law, should be considered. However, as there is a lack of debates on the plasmonic optics applied to RME smart window technology, as research is mainly conducted through an exhaustive process. In this paper, in order to provide insight into the RME-based smart window development and alleviate the unclear part of plasmonic optics applied to the field, finite-difference time-domain electromagnetic simulations are conducted. In total, two extremely low-quality (Cr) and high-quality (Mg) plasmonic materials based on a nanoparticle array are considered as a metal medium. In addition, optical effects caused by the metal active layer, electrolyte, and nanoparticle embedment are investigated in detail. Overall simulations suggest that the effective refractive index is a decisive factor in the performance of RME-based smart windows.
With advancement of technology, requirements for light-emitting devices are increasing. Various types of packaging technologies have been suggested to improve the performance of light-emitting diode (LED). Among them, phosphor in glass (PiG) is attracting attention due to its manufactural facility and easily tunable characteristics. As PiG draws increasing attention, research on glass materials is also being actively conducted. However, studies about glass in the field of phosphor are mainly conducted on fabrication. Only a few studies about recycling have been reported. Thus, the objective of this study was to recycle waste glass discarded in other fields due to breakage and failure and use it to fabricate phosphor in glass. Cylindrical waste glass was pulverized into powder with an average size of 12 μm, mixed with a phosphor and sintered to be reborn as a phosphor in glass to broaden the recycling route for waste glass.
This study investigates the characteristics of a ceramic phosphor (CP) for the converter of a high-power laser diode-based automobile headlamp synthesized by high-frequency induction heated press (HFP) sintering. The CP prepared by an HFP method exhibits remarkable optical properties that are comparable to spark plasma sintering. The effects of post-treatment process for controlling residual pores, as well as sintering temperature, sintering pressure and heating rate for optimization of the HFP sintering method, were studied. The HFP sintering process can be widely used in ceramics and lighting fields because it is designed relatively low cost compared to other techniques and exhibits excellent productivity.
20 January 2025 in Advanced Composites and Hybrid Materials
To obtain environment-friendly and renewable hydrogen energy, research is being actively conducted towards lowering the hydrogen evolution reaction (HER) energy barrier through various modifications to the surface of a transition metal bimetal electrochemical catalyst. Herein, we report the development of highly N-doped carbon shell-encapsulated cobalt iron nano cube (CoFe@HNCS) through fine-tuning of the nitrogen-doping content in the carbon shell. The pyridinic N-rich N-doped carbon shell, achieved by adding melamine through electrostatic interactions, improves conductivity, increases active sites, and optimizes Gibbs free energy for hydrogen adsorption. In alkaline HER performance, the optimized CoFe@HNC20 exhibits a lower overpotential (98.2 mV) than CoFe@NCS (133.2 mV) at 10 mA cm−2. Furthermore, CoFe@HNCS20 as cathode catalyst in anion exchange membrane (AEM) water electrolyzer also shows low cell voltage of 1.808 V to achieve the current density of 0.5 A cm−2. The expansion of the application to combine solar cells and AEM electrolyzer suggests the possibility of a hydrogen ecosystem.