Complex composite films based on polyaniline (PANI) doped hydrochloric acid (HCl) incorporated with aluminum nitrate (Al(NO₃)₃) on Au-layer were designed and synthesized as a surface plasmon resonance (SPR) sensing device. The physicochemical properties of (PANI-HCl)/Al(NO₃)₃ complex composite films were studied for various Al(NO₃)₃ concentrations (0, 2, 4, 8, 16, and 32 wt.%). The refractive index of the (PANI-HCl)/Al(NO₃)₃ complex composite films increased continuously as Al(NO₃)₃ concentrations increased. The electrical conductivity values increased from 5.10 µS/cm to 10.00 µS/cm as Al(NO₃)₃ concentration increased to 32 wt.%. The sensitivity of the SPR sensing device was investigated using a theoretical approach and experimental measurements. The theoretical system of SPR measurement confirmed that increasing Al(NO₃)₃ in (PANI-HCl)/Al(NO₃)₃ complex composite films enhanced the sensitivity from about 114.5 [Deg/RIU] for Au-layer to 159.0 [Deg/RIU] for Au-((PANI-HCl)/Al(NO₃)₃ (32 wt.%)). In addition, the signal-to-noise ratio for Au-layer was 3.95, which increased after coating by (PANI-HCl)/Al(NO₃)₃ (32 wt.%) complex composite layer to 8.82. Finally, we conclude that coating Au-layer by (PANI-HCl)/Al(NO₃)₃ complex composite films enhances the sensitivity of the SPR sensing device.

This study synthesized carbon quantum dots (CQDs) with green photoluminescence through a hydrothermal method that utilized mulberry juice as the carbon source. The influence of fruit ripeness on the physical and chemical properties, focusing on the fluorescence spectra, has been explored. Fourier-transform infrared spectroscopy (FT-IR) and energy dispersive X-ray analysis (EDX) showed that there were oxygen-containing groups, and X-ray diffraction (XRD) showed that the carbon quantum dots (CQDs) were graphitic. The results revealed that the CQDs had an average size of around 7.4nm and 9.7nm for unripe and ripe mulberry juice, respectively. These CQDs emitted green light at 500nm and 510nm in unripe and ripe mulberry juice, respectively, when excited at a wavelength of 400nm. The prepared CQDs exhibited excitation-dependent photoluminescence (PL) emission behavior, demonstrating their dependence on the excitation light. The impact of fruit ripeness on optical properties was explored by examining fluorescent spectra from different fruits (including tomato and blackberry), demonstrating comparable behaviors observed in mulberry fruit. In addition, the prepared CQDs were utilized as a fluorescent sensor with high specificity to detect Cu²⁺ ions. The detection limit (DL) for this sensor was determined to be 0.2687µM, and the limit of qualification (LOQ) is 0.814µM. The linear range for detection lies between 0.1 and 1µM. The selectivity of the CQDs towards Cu²⁺ ions was confirmed by recording the PL response for Cu²⁺ ions compared to the weak response of other metal ions. According to these results, the CQDs can be applied in various cellular imaging and biology applications, bio-sensing, optoelectronics, and sensors.

This paper investigates the characteristics some of argon plasma parameters of glow discharge under axial magnetic field. The DC power supply of range (0-6000) V is used as a breakdown voltage to obtain the discharge of argon gas. The discharge voltage-current (V-I) characteristic curves and Paschen’s curves as well as the electrical conductivity were studied with the presents of magnetic field confinement at different gas pressures. The magnetic field up to 25 mT was obtained using four coils of radius 6 cm and 320 turn by passing A.C current up to 5 Amperes. Spectroscopic measurements are employed for purpose of estimating two main plasma parameters electron temperature (Te) and electron density (ne). Emission spectra from positive column (PC) zone of the discharge have been studies at different values of magnetic field and pressures at constant discharge currents of 1.5 mA. Electron temperature (Te) and its density are calculated from the ratio of the intensity of two emission lines of the same lower energy levels. Experimental results show the abnormal glow region characteristics (positive resistance). Breakdown voltage versus pressure curves near the curves of paschen and decrease as magnetic field increases due to magnetic field confinement of plasma charged particles. Also the electrical conductivity increases due to enhancing magnetic field at different gas pressures. Both temperature density of electron and the intensities of two selected emission lines decrease with increasing pressure due decreasing of mean free path of electron. Electron density increase according to enhancing magnetic field, while the intensity of emitting lines tends to decrease.