Two iron-rich clayey materials (L1 and L2, with the main difference being the level of iron accumulation) have been studied for their suitability as solid precursors for inorganic polymer composites. L1, with the lower iron content, was calcined at 700°C for 4 h and used as replacement, in the range of 15–35 wt%, for both raw laterites in the formulations of geopolymeric composites. The different mixtures were activated with a highly concentrated alkaline solution containing sodium hydroxide and sodium silicate. River sand with semi-crystalline structure was added to form semi-dry pastes which were pressed to appropriate shape. X-ray diffraction, Infrared spectroscopy, Scanning Electron Microscopy and Mercury Intrusion Porosimetry results demonstrated the effectiveness of the calcined fraction of L1 to act as nucleation sites and extend the geopolymerization to the matrix composites. A highly compact matrix with low porosity and good stability in water, together with a strength comparable to that of standard concretes was obtained allowing for conclusions to be made on the quality of laterites as promising solid precursor for sustainable, environmentally-friendly, and cost-efficient structural materials.

Lateritic soils are formed in the tropics through weathering processes that favor the formation of iron, aluminum, manganese and titanium oxides. These processes break down silicate minerals into clay minerals such as kaolinite and illite. Iron and aluminum oxides are prominent in lateritic soils, and with the seasonal fluctuation of the water table, these oxides result in the reddish-brown color that is seen in lateritic soils. These soils have served for a long time as major and sub-base materials for the construction of most highways and walls of residential houses in tropical and sub-tropical countries of the world. Civil engineering applications of these lateritic soils are continually being developed with the use of different types of stabilizers. The stabilized soil-based products are as such viewed as environmentally-friendly and low-cost energy materials for sustainable building applications. This work aims at presenting a global view of what has been done in the field of lateritic soil improvement for construction purposes in tropical countries such as Cameroon. This shall be discussed through the presentation of the structure, composition and properties of lateritic soils, the various ways of improving their properties for construction purposes, the properties of products obtained and other prospects.

Because of concerns over the construction industry‘s heavy use of cement and the general dissatisfaction with the performance of building envelopes with respect to durability, there is a growing demand for a novel class of ―green‖ binders. Geopolymer binders have re-emerged as binders that can be used as a replacement for Portland cement given their numerous advantages over the latter including lower carbon dioxide emissions, greater chemical and thermal resistance, combined with enhanced mechanical properties at both normal and extreme exposure conditions. The paper focuses on the use of geopolymer binders in building applications. It discusses the various options for starting materials and describes key engineering properties associated with geopolymer compositions that are ideal for structural applications. Specific properties, such as compressive strength, density, pore size distribution, cumulative water absorption, and acid resistance, are comparable to the specifications for structures incorporating conventional binders. This paper presents geopolymer binders, with their three dimensional microstructure, as material for structural elements that can be used to advance the realization of sustainable building systems.