Maria Teresa Garcia

Dr. Maria Teresa Garcia

IQAC CSIC, Barcelona, Catalonia, Spain
orcid

Research Focus & Metrics

Academic Career Length

36Years (1991-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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13 December 2004 in Green Chemistry
Verified
Journal Article
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MGMaria Teresa Garcia
Maria Teresa Garcia
NGNick Gathergood
Nick Gathergood
PSPeter J. Scammells
Peter J. Scammells
Although ionic liquids are generally referred to in a ‘green’ context, little is known about their degradation in the environment. Part I of this series focused on the biodegradability of the commonly used dialkylimidazolium ionic liquids and the effect of the imidazolium cation on biodegradability. We now report the influence of the anion on biodegradability. Preliminary investigations into the toxicology of ionic liquids are also described.

4 February 2004 in Green Chemistry
Verified
Journal Article
Closed access
PDF file
NGNick Gathergood
Nick Gathergood
MGMaria Teresa Garcia
Maria Teresa Garcia
PSPeter J. Scammells
Peter J. Scammells
The design, preparation and evaluation of biodegradable ionic liquids containing ester or amide groups in the alkyl side chain are presented. Factors improving the biodegradation of surfactants were successfully applied to ionic liquids. These novel ionic liquids can be prepared from readily available starting materials in high yield. The introduction of a group susceptible to enzymatic hydrolysis greatly improves the biodegradation (OECD 301D ‘Closed Bottle Test’) compared with the commonly used dialkylimidazolium ionic liquids, bmimBF4 and bmimPF6 . For the 3-methyl-1-(alkyloxycarbonylmethyl)imidazolium bromide series, the greatest biodegradation was observed when alkyl = butyl, pentyl, hexyl and octyl. The corresponding amide analogs proved to be poorly biodegradable.

1 March 2011 in Journal of Colloid and Interface Science
Verified
Journal Article
Closed access
ACAnna Cornellas
Anna Cornellas
LPLourdes Perez
Lourdes Perez
FCFrancesc Comelles
Francesc Comelles
IRIsabel Ribosa
Isabel Ribosa
AMAngeles Manresa
Angeles Manresa
MGMaria Teresa Garcia
Maria Teresa Garcia

13 January 2006 in Green Chemistry
Verified
Journal Article
Closed access
PDF file
NGNick Gathergood
Nick Gathergood
PSPeter J. Scammells
Peter J. Scammells
MGMaria Teresa Garcia
Maria Teresa Garcia
Further research toward the discovery of biodegradable ionic liquids (ILs) is described herein. The biodegradability of the target ILs was evaluated using the ‘Closed Bottle’ and ‘CO2 Headspace’ tests (OECD 301D and ISO 14593). This research has identified the first ILs which can be classified as ‘readily biodegradable’ under aerobic conditions.

26 March 2004 in Green Chemistry
Verified
Journal Article
Closed access
PDF file
M. Carmen MoránM. Carmen Morán
M. Carmen Morán
APAurora Pinazo
Aurora Pinazo
LPLourdes Perez
Lourdes Perez
PCPere Clapes
Pere Clapes
MAMarta Angelet
Marta Angelet
MIMa Rosa Infante
Ma Rosa Infante
The value of amino acids and vegetable oil derivatives as raw materials for the preparation of surfactants was recognized as soon as they were discovered early in the last century. Amino acid-based surfactants, which have an amino acid residue as a hydrophilic moiety, are reviewed with respect to their synthesis, properties and some applications. The review covers three main categories of amino acid-based surfactants: Nα-acyl, N-alkyl amide and O-alkyl ester derivatives among the linear or single chain amino acid-based surfactants; Nα, Nω-bis(Nα-acylarginine)α,ω-alkylendiamides, which are gemini amino acid-based surfactants; and 1-monoacyl-rac-glycero-3-O-(Nα-acetyl-L-amino acid) and 1,2-diacyl-rac-glycero-3-O-(Nα-acetyl-L-amino acid), both amino acid-based surfactants with glycerolipid-like structures.

11 February 2013 in Langmuir
Verified
Journal Article
Closed access
MGMaria Teresa Garcia
Maria Teresa Garcia
IRIsabel Ribosa
Isabel Ribosa
LPLourdes Perez
Lourdes Perez
AMAngeles Manresa
Angeles Manresa
FCFrancesc Comelles
Francesc Comelles