Biofilms are known to be difficult to eradicate and control, complicating human infections and marine biofouling. In this study, self-polishing and anti-fouling waterborne polyurethane coatings synthesized from gemini quaternary ammonium salts (GQAS), polyethylene glycol (PEG), and polycaprolactone diol (PCL) demonstrate excellent antibiofilm efficacy. Their anti-fouling and anti-biofilm performance was confirmed by a culture-based method in broth media, with the biofilm formation factor against Gram-positive (S. aureus) and Gram-negative bacterial strains (E. coli) for 2 days. The results indicate that polyurethane coatings have excellent anti-biofilm activity when the content of GQAS reached 8.5 wt% against S. aureus, and 15.8 wt% against E. coli. The resulting waterborne polyurethane coatings demonstrate both hydrolytic and enzymatic degradation, and the surface erosion enzymatic degradation mechanism enables them with good self-polishing capability. The extracts cyto-toxicity of these polyurethane coatings and degradation liquids was also systematically studied; they could be degraded to non-toxic or low toxic compositions. This study shows the possibility to achieve potent self-polishing and anti-biofilm efficacy by integrating antibacterial GQAS, PEG, and PCL into waterborne polyurethane coatings.
Titanium foam has been the focus of special attention for its specific structure and potential applications in purification, catalyst substrate, heat exchanger, biomaterial, aerospace and naval industries. However, the liquid-state foaming techniques are difficult to use in fabricating Ti foam because of its high melting temperature and strong chemical reactivity with atmospheric gases. Here, the fabrication of Ti foams via the powder metallurgy route was carried out by utilizing both magnesium powders and magnesium particles as spacer holders, and Ti powders as matrix metal. The green compacts containing Ti powder, Mg powder and Mg particles were heated to a certain temperature to remove the magnesium and obtain the Ti foam. The results show that the porosities of the obtained Ti foam are about 35–65%, and Young’s modulus and yield strength are found to be in the ranges of 22–126 MPa and 0.063–1.18 GPa, respectively. It is found that the magnesium powders play a more important role than the magnesium particles in the deformation and the densification of the green compact during the pressing, and the pore structure of Ti foam depends on the amount and the size of the magnesium spacer holders after sintering.
This study introduces a novel Ni/NiCr/NiCrAlSi composite coating to enhance the corrosion resistance of copper, particularly for its use in marine heat exchangers. Utilizing characterization techniques such as scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS), the paper investigates the coating’s composition, structure, and corrosion resistance in 3.5 wt.% NaCl aqueous solutions. A significant focus is placed on the role of aluminum within the NiCrAlSi layer, examining its influence on the coating’s structure and corrosion behavior. The results indicate that the NiCrAlSi layer with an aluminum content of 5.49 at.% exhibits the most improved corrosion resistance, characterized by the highest corrosion potential and a corrosion current density that is more than one order of magnitude lower compared to the Ni/NiCr coating. The effectiveness of this composite coating is attributed to its multilayer structure and the synergistic effect of alloying elements Cr, Al, and Si, which collectively inhibit corrosive medium penetration. These insights present the Ni/NiCr/NiCrAlSi coating as a promising candidate for copper protection in sea water environments, merging enhanced durability with cost-effectiveness.
Aiming at the goal of preparing high-quality coatings, this paper reviews the progress on circular arc source structure and magnetic field arc controlling technology in arc ion plating (AIP), with a focus on design characteristics of the different structures and configuration optimization of the corresponding magnetic fields. The circular arc source, due to its simple structure, convenient installation, flexible target combination, high cooling efficiency, and high ionization rate and deposition rate, has shown significant application potential in AIP technology. In terms of magnetic field arc controlling technology, this paper delves into the design progress of various magnetic field configurations, including fixed magnetic fields generated by permanent magnets, dynamic rotating magnetic fields, axially symmetric magnetic fields, rotating transverse magnetic fields, and multi-mode alternating electromagnetic coupling fields. By designing the magnetic field distribution reasonably, the trajectory and velocity of the arc spot can be controlled precisely, thus reducing the generation of macroparticles, improving target utilization, and enhancing coating uniformity. In particular, the introduction of multi-mode magnetic field coupling technology has broken through the limitations of traditional single magnetic field structures, achieving comprehensive optimization of arc spot motion and plasma transport. Hopefully, these research advances provide an important theoretical basis and technical support for the application of AIP technology in the preparation for high-quality decorative and functional coatings.
The incorporation of a homogeneously distributed nanocrystalline phase in Fe-based amorphous coatings is widely acknowledged to enhance wear resistance across various applications. In this study, FeCrMoWBRE amorphous/nanocrystalline composite coatings were fabricated on 45# steel substrates using high-velocity arc spraying (HVAS). The coatings were produced under varying spraying voltages, currents, and distances, following the Taguchi experimental design methodology. The microstructure, mechanical properties, and wear resistance of the coatings were systematically analyzed, with a particular focus on the relationship between nanocrystalline/amorphous phase content and key performance metrics, including microhardness, adhesive strength, and wear rate. A positive correlation was observed between the nanocrystalline phase content and both mechanical properties and wear resistance. The coating with optimized nanocrystalline phase content of 21.4% exhibits the lowest wear rate of 1.39 × 10−7 mm3·N−1·m−1 under a 100 N load and oil lubrication. These findings underscore the critical role of controlling the nanocrystalline phase content in Fe-based amorphous/nanocrystalline composite coatings to maximize wear resistance under oil-lubricated conditions.