The depletion of fossil fuels in the current world has been a major concern due to their role as a primary source of energy for many countries. As non-renewable sources continue to deplete, there is a need for more research and initiatives to reduce reliance on these sources and explore better alternatives, such as renewable energy. Hydrogen is one of the most intriguing energy sources for producing power from fuel cells and heat engines without releasing carbon dioxide or other pollutants. The production of hydrogen via the electrolysis of water using renewable energy sources, such as solar energy, is one of the possible uses for solid oxide electrolysis cells (SOECs). SOECs can be classified as either oxygen-ion conducting or proton-conducting, depending on the electrolyte materials used. This article aims to highlight broad and important aspects of the hybrid SOEC-based solar hydrogen-generating technology, which utilizes a mixed-ion conductor capable of transporting both oxygen ions and protons simultaneously. In addition to providing useful information on the technological efficiency of hydrogen production in SOEC, this review aims to make hydrogen production more efficient than any other water electrolysis system.

The recovery of fibres from waste paper (WP) and deinking sludge (DIS) reduces the stress on nature compared to the collection of virgin pulp for paper production. Moreover, if not recycled, WP and DIS are mainly landfilled and incinerated, being thus responsible for the release of greenhouse gases (GHGs) into the atmosphere. In this context, energy recovery from WP and DIS would contribute to increasing energy independence and improving waste management in the pulp industry. From a broader perspective, it would increase renewable energy generation, supporting the paper industry in reducing fossil fuel consumption and GHGs emissions, in line with the goals of the European Union (EU) Green Deal 2021. For these reasons, in the present study, the combined heat and power generation potentiality of WP–DIS blends through gasification in combination with an internal combustion engine is numerically assessed for the first time. The air gasification process is simulated by applying a restricted chemical equilibrium approach to identify the optimum operating temperature (850 °C) and equivalence ratio (0.2). Electrical and thermal energy generation potentiality, considering WP and DIS production in the EU in 2019, is estimated to be in the ranges of 32,950–35,700 GWh and 52,190–56,100 GWh, respectively. Thus, it can support between 25 and 28% of the electrical and 44–48% of the thermal energy demand of the paper manufacturing sector, reducing the CO₂ emission in the range of 24.8–28.9 Gt.