Porous carbon materials have demonstrated exceptional performance in various energy and environment-related applications. Recently, research on supercapacitors has been steadily increasing, and porous carbon materials have emerged as the most significant electrode material for supercapacitors. Nonetheless, the high cost and potential for environmental pollution associated with the preparation process of porous carbon materials remain significant issues. This paper presents an overview of common methods for preparing porous carbon materials, including the carbon-activation method, hard-templating method, soft-templating method, sacrificial-templating method, and self-templating method. Additionally, we also review several emerging methods for the preparation of porous carbon materials, such as copolymer pyrolysis, carbohydrate self-activation, and laser scribing. We then categorise porous carbons based on their pore sizes and the presence or absence of heteroatom doping. Finally, we provide an overview of recent applications of porous carbon materials as electrodes for supercapacitors.

Since the initial discovery of Ti₃C₂ a decade ago, there has been a significant surge of interest in 2D MXenes and MXene‐based composites. This can be attributed to the remarkable intrinsic properties exhibited by MXenes, including metallic conductivity, abundant functional groups, unique layered microstructure, and the ability to control interlayer spacing. These properties contribute to the exceptional electrical and mechanical performance of MXenes, rendering them highly suitable for implementation as candidate materials in flexible and wearable energy storage devices. Recently, a substantial number of novel research has been dedicated to exploring MXene‐based flexible materials with diverse functionalities and specifically designed structures, aiming to enhance the efficiency of energy storage systems. In this review, a comprehensive overview of the synthesis and fabrication strategies employed in the development of these diverse MXene‐based materials is provided. Furthermore, an in‐depth analysis of the energy storage applications exhibited by these innovative flexible materials, encompassing supercapacitors, Li‐ion batteries, Li–S batteries, and other potential avenues, is conducted. In addition to presenting the current state of the field, the challenges encountered in the implementation of MXene‐based flexible materials are also highlighted and insights are provided into future research directions and prospects.

Hydrogen, a renewable and recyclable energy, has been regarded as the best solution for global energy supply in the 21^st century. Hydrogen production, hydrogen storage and hydrogen sensing are three most important aspects for hydrogen economy. Interestingly, the lightest solid, carbon aerogels (CAs), has found wide applications in these aspects due to its unique characteristics including large specific surface area, hierarchical porous structure, high electrical conductivity, superb chemical stability, and low fabrication cost. Herein, various fabrication strategies of CAs are presented, and their applications in the three most important aspects are comprehensively reviewed. In addition, the challenges and prospects are also discussed. In the light of the recent progress in CAs for hydrogen-related applications, this review provides a comprehensive assessment on materials selection, synthesis, hydrogen adsorption characteristics of CAs and catalytic activity of CA-supported nanocatalysts, offering a strategic guide to build a close connection between CAs and hydrogen economy.