The titanium carbide MXenes currently attract an extreme amount of interest from the material science community due to their promising functional properties arising from the two-dimensionality of these layered structures. In particular, the interaction between MXene and gaseous molecules, even at the physisorption level, yields a substantial shift in electrical parameters, which makes it possible to design gas sensors working at RT as a prerequisite to low-powered detection units. Herein, we consider to review such sensors, primarily based on Ti₃C₂T_x and Ti₂CT_x crystals as the most studied ones to date, delivering a chemiresistive type of signal. We analyze the ways reported in the literature to modify these 2D nanomaterials for (i) detecting various analyte gases, (ii) improving stability and sensitivity, (iii) reducing response/recovery times, and (iv) advancing a sensitivity to atmospheric humidity. The most powerful approach based on designing hetero-layers of MXenes with other crystals is discussed with regard to employing semiconductor metal oxides and chalcogenides, noble metal nanoparticles, carbon materials (graphene and nanotubes), and polymeric components. The current concepts on the detection mechanisms of MXenes and their hetero-composites are considered, and the background reasons for improving gas-sensing functionality in the hetero-composite when compared with pristine MXenes are classified. We formulate state-of-the-art advances and challenges in the field while proposing some possible solutions, in particular via employing a multisensor array paradigm.

The in-situ Raman spectroscopy oxidation of the accordion-like V₂CT_x MXene has been studied. It was found that a nanocomposite of V₂CT_x/V₃O₇ composition was formed as a result. The elemental and phase composition, the microstructure of the synthesized V₂CT_x powder and MXene film as well as the V₂CT_x/V₃O₇ nanocomposite obtained at a minimum oxidation temperature of 250 °C were studied using a variety of physical and chemical analysis methods. It was found that the obtained V₂CT_x and V₂CT_x/V₃O₇ films have an increased sensitivity to ammonia and nitrogen dioxide, respectively, at room temperature and zero humidity. It was shown that the V₂CT_x/V₃O₇ composite material is characterized by an increase in the response value for a number of analytes (including humidity) by more than one order of magnitude, as well as a change in their detection mechanisms compared to the individual V₂CT_x MXene.

At present, a new class of 2D nanomaterials, MXenes, is of great scientific and applied interest, and their application prospects are very broad, including as effective doping components for receptor materials of MOS sensors. In this work we have studied the influence on the gas-sensitive properties of nanocrystalline zinc oxide synthesized by atmospheric pressure solvothermal synthesis, with the addition of 1–5% of multilayer two-dimensional titanium carbide Ti₂CT_x, obtained by etching Ti₂AlC with NaF solution in hydrochloric acid. It was found that all the obtained materials have high sensitivity and selectivity with respect to 4–20 ppm NO₂ at a detection temperature of 200 °C. It is shown that the selectivity towards this compound is best for the sample containing the highest amount of Ti₂CT_x dopant. It has been found that as the MXene content increases, there is an increase in nitrogen dioxide (4 ppm) from 1.6 (ZnO) to 20.5 (ZnO-5 mol% Ti₂CT_x). reactions which the responses to nitrogen dioxide increase. This may be due to the increase in the specific surface area of the receptor layers, the presence of MXene surface functional groups, as well as the formation of the Schottky barrier at the interface between the phases of the components.

The 2D structure of MXenes attracts wide research attention toward an application of these materials in gas sensors. These structures are extremely sensitive to minor variations in their composition, which are employed for tuning their functional properties. Here, we consider the partially substituted MXenes of the composition of Ti_xV_2-xC, where x = 0.2, via quantum chemical calculations, and test their chemiresistive characteristics as a receptor component of the planar-type sensor and on-chip multisensor array. We thoroughly discuss the synthesis process of Ti_0.2V_1.8AlC MAX-phase and the corresponding MXenes, to prepare functional inks and, furthermore, deposit the films by microextrusion printing over an array of planar multi-electrode structures at the surface of a pen-sized chip. The crystal structure of the obtained materials is evaluated via X-ray diffraction analysis. The developed chip has been exposed upon few gaseous analytes, of alcohol VOCs, NH₃, and H₂O, of a 500–16,000 ppm concentration, at room temperature to ensure that we could observe the positive chemiresistive effect matured from resistance enhancing, with up to 10% vs. water vapors. The calculations carried in the framework of the density-functional theory for V₂C, Ti₂C, and Ti_0.2V_1.8C crystals ensured that the variations in their electronic structure were almost consistent with the experiment fundings: the most prominent effect is observed in relation to the H₂O vapors. Therefore, these Ti_0.2V_1.8C structures could be considered for applying them in room temperature-operated hygrometers.