Diamond properties down to the quantum-size region are still poorly understood. High-pressure high-temperature (HPHT) synthesis from chloroadamantane molecules allows precise control of nanodiamond size. Thermal stability and optical properties of nanodiamonds with sizes spanning range from <1 to 8 nm are investigated. It is shown that the existing hypothesis about enhanced thermal stability of nanodiamonds smaller than 2 nm is incorrect. The most striking feature in IR absorption of these samples is the appearance of an enhanced transmission band near the diamond Raman mode (1332 cm${}^{-1}$). Following the previously proposed explanation, we attribute this phenomenon to the Fano effect caused by resonance of the diamond Raman mode with continuum of conductive surface states. We assume that these surface states may be formed by reconstruction of broken bonds on the nanodiamond surfaces. This effect is also responsible for the observed asymmetry of Raman scattering peak. The mechanism of nanodiamond formation in HPHT synthesis is proposed, explaining peculiarities of their structure and properties.

ZnO/Fe₂O₃ nanocomposites with different concentration and thickness of the Fe₂O₃ layer were obtained by two-stage aerosol vapor deposition (AACVD). It was shown that the ZnO particles have a wurtzite structure with an average size of 51–66 nm, and the iron oxide particles on the ZnO surface have a hematite structure and an average size of 23–28 nm. According to EDX data, the iron content in the films was found to be 1.3–5.8 at.%. The optical properties of the obtained films were studied, and the optical band gap was found to be 3.16–3.26 eV. Gas-sensitive properties at 150–300 °C were studied using a wide group of analyte gases: CO, NH₃, H₂, CH₄, C₆H₆, ethanol, acetone, and NO₂. A high response to 100 ppm acetone and ethanol at 225–300 °C and a high and selective response to 300–2000 ppb NO₂ at 175 °C were established. The effect of humidity on the magnitude and shape of the signal obtained upon NO₂ detection was studied.

The in-situ Raman spectroscopy oxidation of the accordion-like V₂CT_x MXene has been studied. It was found that a nanocomposite of V₂CT_x/V₃O₇ composition was formed as a result. The elemental and phase composition, the microstructure of the synthesized V₂CT_x powder and MXene film as well as the V₂CT_x/V₃O₇ nanocomposite obtained at a minimum oxidation temperature of 250 °C were studied using a variety of physical and chemical analysis methods. It was found that the obtained V₂CT_x and V₂CT_x/V₃O₇ films have an increased sensitivity to ammonia and nitrogen dioxide, respectively, at room temperature and zero humidity. It was shown that the V₂CT_x/V₃O₇ composite material is characterized by an increase in the response value for a number of analytes (including humidity) by more than one order of magnitude, as well as a change in their detection mechanisms compared to the individual V₂CT_x MXene.

At present, a new class of 2D nanomaterials, MXenes, is of great scientific and applied interest, and their application prospects are very broad, including as effective doping components for receptor materials of MOS sensors. In this work we have studied the influence on the gas-sensitive properties of nanocrystalline zinc oxide synthesized by atmospheric pressure solvothermal synthesis, with the addition of 1–5% of multilayer two-dimensional titanium carbide Ti₂CT_x, obtained by etching Ti₂AlC with NaF solution in hydrochloric acid. It was found that all the obtained materials have high sensitivity and selectivity with respect to 4–20 ppm NO₂ at a detection temperature of 200 °C. It is shown that the selectivity towards this compound is best for the sample containing the highest amount of Ti₂CT_x dopant. It has been found that as the MXene content increases, there is an increase in nitrogen dioxide (4 ppm) from 1.6 (ZnO) to 20.5 (ZnO-5 mol% Ti₂CT_x). reactions which the responses to nitrogen dioxide increase. This may be due to the increase in the specific surface area of the receptor layers, the presence of MXene surface functional groups, as well as the formation of the Schottky barrier at the interface between the phases of the components.