Francesca Alessandro

Dr. Francesca Alessandro

Institute on Membrane Technology (ITM-CNR), 87036 Rende, Italy
orcid

Research Focus & Metrics

Academic Career Length

9Years (2018-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
12 July 2025 in Materials
Verified
Journal Article
Open access
PDF file
Francesca AlessandroFrancesca Alessandro
Francesca Alessandro
Francesca MacedonioFrancesca Macedonio
Francesca Macedonio
Membrane distillation (MD) has attracted increasing attention as a thermally driven separation process for water purification, desalination, and wastewater treatment. Its primary advantages include high rejection of non-volatile solutes, compatibility with low-grade or waste heat sources, and operation at ambient pressure. Despite these benefits, large-scale implementation remains limited due to the lack of membrane materials capable of withstanding harsh operating conditions and maintaining their hydrophobic character. Polymeric membranes have traditionally been used in MD applications; however, their limited thermal and chemical stability compromises long-term performance and reliability. In contrast, ceramic membranes are emerging as a promising alternative, offering superior mechanical strength, chemical resistance, and thermal stability. Nevertheless, their broader adoption in MD is hindered by several challenges, including high thermal conductivity, surface wettability, high fabrication costs, and limited scalability. This review provides a critical assessment of current developments, key opportunities, and ongoing challenges associated with the use of ceramic membranes in MD. Particular emphasis is placed on advances in surface modification techniques and the emerging applications in advanced MD configurations.

21 February 2023 in Membranes
Verified
Journal Article
Open access
PDF file
Francesca AlessandroFrancesca Alessandro
Francesca Alessandro
Francesca MacedonioFrancesca Macedonio
Francesca Macedonio
Enrico DrioliEnrico Drioli
Enrico Drioli
Water scarcity raises important concerns with respect to human sustainability and the preservation of important ecosystem functions. To satisfy water requirements, seawater desalination represents one of the most sustainable solutions. In recent decades, membrane distillation has emerged as a promising thermal desalination process that may help to overcome the drawbacks of traditional desalination processes. Nevertheless, in membrane distillation, the temperature at the feed membrane interface is significantly lower than that of the bulk feed water, due to the latent heat flux associated with water evaporation. This phenomenon, known as temperature polarization, in membrane distillation is a crucial issue that could be responsible for a decay of about 50% in the initial transmembrane water flux. The use of plasmonic nanostructures, acting as thermal hotspots in the conventional membranes, may improve the performance of membrane distillation units by reducing or eliminating the temperature polarization problem. Furthermore, an efficient conversion of light into heat offers new opportunities for the use of solar energy in membrane distillation. This work summarizes recent developments in the field of plasmonic-enhanced solar evaporation with a particular focus on solar-driven membrane distillation applications and its potential prospects.

9 January 2019 in Physical Review B
Verified
Journal Article
Closed access
PDF file
BGBarun Ghosh
Barun Ghosh
Francesca AlessandroFrancesca Alessandro
Francesca Alessandro
MZMarilena Zappia
Marilena Zappia
RBRosaria Brescia
Rosaria Brescia
CKChia-Nung Kuo
Chia-Nung Kuo
ACAnna Cupolillo
Anna Cupolillo
We explore the broadband excitation spectrum of bulk PtTe2 using electron energy-loss spectroscopy and density-functional theory. In addition to infrared modes related to intraband three-dimensional (3D) Dirac plasmon and interband transitions between the 3D Dirac bands, we observe modes at 3.9, 7.5, and 19.0 eV in the ultraviolet region. The comparison of the excitation spectrum with the calculated orbital-resolved density of states allows us to ascribe spectral features to transitions between specific electronic states. Additionally, we study the thickness dependence of the high-energy-loss peak in the PtTe2 thin films. We show that, unlike graphene, the high-energy EELS peak in PtTe2 thin film gets redshifted by ∼2.5 eV with increasing thickness.

6 June 2018 in Nanotechnology
Verified
Journal Article
Closed access
Francesca AlessandroFrancesca Alessandro
Francesca Alessandro
ASA Scarcello
A Scarcello
MVM D Basantes Valverde
M D Basantes Valverde
DFD C Coello Fiallos
D C Coello Fiallos
SOS M Osman
S M Osman
Lorenzo CaputiLorenzo Caputi
Lorenzo Caputi
Carbon nano-onions (CNOs), in their spherical or polyhedral forms, represent an important class of nanomaterials, due to their peculiar physical and electrochemical properties. Among the different methods of production, arc discharge between graphite electrodes sustained by deionized water is one of the most promising to obtain good quality CNOs in gram quantities. We applied the method with the aim to optimize the production of CNOs, using an innovative experimental arrangement. The discharges generate dispersed nanomaterials and a black hard cathodic deposit, which were studied by transmission electron microscopy–high-resolution TEM, scanning electron microscopy, Raman, thermogravimetric analysis and energy-dispersive x-ray spectroscopy. A simple mechanical grinding of the deposits permitted us to obtain turbostratic polyhedral CNOs that exhibited higher stability towards burning in air, compared to CNOs found in water. We propose a mechanism for the formation of the CNOs present in the deposit, in which the crystallization is driven by a strong temperature gradient existing close to the cathode surface at the beginning of the process, and subsequently close to the deposit surface whenever it is growing.

2 January 2023 in Chemistry
Verified
Journal Article
Open access
PDF file
Francesca AlessandroFrancesca Alessandro
Francesca Alessandro
Francesca MacedonioFrancesca Macedonio
Francesca Macedonio
Enrico DrioliEnrico Drioli
Enrico Drioli
In recent decades, membrane-based processes have been extensively applied to a wide range of industrial processes, including gas separation, food industry, drug purification, and wastewater treatment. Membrane distillation is a thermally driven separation process, in which only vapour molecules transfer through a microporous hydrophobic membrane. At the operational level, the performance of membrane distillation is negatively affected by wetting and temperature polarization phenomena. In order to overcome these issues, advanced membranes have been developed in recent years. This review, which focuses specifically on membrane distillation presents the basic concepts associated with the mass and heat transfer through hydrophobic membranes, membrane properties, and advances in membrane materials. Photothermal materials for solar-driven membrane distillation applications are also presented and discussed.

12 June 2022 in Journal of Membrane Science
Verified
Journal Article
Closed access
SCS. Capizzano
S. Capizzano
MFMirko Frappa
Mirko Frappa
Enrico DrioliEnrico Drioli
Enrico Drioli
Francesca AlessandroFrancesca Alessandro
Francesca Alessandro
Francesca MacedonioFrancesca Macedonio
Francesca Macedonio