Corrosion behavior of Hastelloy C-22, Ti-0.2Pd and Ti-32Mo alloys in the aqueous solution of hydrochloric acid and sodium chlorate was investigated. The C-22 alloy was pitted because the intergranular carbides rich in Cr and Mo would lead to the lack of corrosion-resistant elements in the adjacent area. The Ti-0.2Pd alloy was pitted because the passivation trend decreased in reducing solution and Cl− broke through the passivation film. The weigh loss rate and corrosion depth of Ti-0.2Pd alloy increased sharply after pitting corrosion, which was due to the rapid corrosion of the materials exposed inside by the corrosion medium. The Ti-32Mo alloy was pitted due to the transpassivation of Mo caused by NaClO3. In the process of corrosion, the products of reaction between Mo and Cl− formed an insoluble and dense protective film, which slowed down the corrosion rate of Ti-32Mo, that is why the weigh loss rate and corrosion depth increased slowly even if pitting corrosion happened.
In order to find a short, economically feasible process for chalcopyrite preconcentration and to provide a reference for the preconcentration of similar copper sulfide ores, the particle size characteristics of the crushed products from a high-pressure grinding roller (HPGR) and jaw crusher (JC) were analyzed, as well as the liberation degree and fracture characteristics of the chalcopyrite. The float–sink test (FST) was carried out on the crushed products, and the effects of the two crushing methods on the FSTs of the crushed products were compared. The research results show that at the same crushing fineness, the chalcopyrite liberation in HPGR products can be enhanced by 14%~18% compared with the JC. The single-particle crushing of the JC tends to produce intergranular fracturing of chalcopyrite, while the lamination crushing of the HPGR produces more transgranular fracturing of chalcopyrite; the chalcopyrite in the −5 + 0.5 mm size fraction mainly produces intergranular fracturing, and the chalcopyrite in the −0.5 mm size fraction mainly produces transgranular fracturing. The FST results show that heavy media preconcentration was suitable for chalcopyrite, and, in the optimal conditions of a size fraction of −3 + 0.5 mm and separation density of 2.55 g/cm3, the grade and distribution rate of Cu in the sinks obtained by HPGR-FST were 0.35% and 89.86%, respectively, and the floats yield was 24.76%, with a better enrichment of sinks and higher floats yields, which was better when compared with that of the JC-FST.
27 February 2025 in Mining, Metallurgy & Exploration
In order to rationalize the development and utilization of the wall rock discarded during rare earth mining, chemical analysis, inductively coupled plasma-atomic emission spectroscopy, X-ray diffraction analysis, artificial panning, optical microscope analysis, mineral liberation analysis and...
Intensive calcination, selection and metallurgical joint comprehensive utilization of solid waste blast furnace gas ash generated by a Chinese iron and steel plant. The main valuable elements in the gas ash are Fe, Pb, Zn, and C, with contents of 22.46%, 3.22%, 10.57%, and 27.02%, respectively. The iron minerals are mainly magnetite and hematite/limonite. Lead exists primarily in the form of lead vanadate and basic lead chloride. Zinc is associated with oxygen, sulfur, and iron in the form of zinc ferrite crystals. The effects of calcination temperature, calcination time, and reducing agent dosage on gasification and reduction indices were investigated. Results showed that using a gasification and reduction calcination–magnetic separation process with weak magnetism, at a calcination temperature of 1150 °C, with 20% anthracite as the reducing agent and a calcination time of 2 h, the volatilization rates of lead and zinc reached 96.70% and 98.26%, respectively. When the roasted ore was ground to a particle size of D90 = 0.085 mm, high-quality iron concentrate with 65.61% iron grade and low lead and zinc contents of 0.08% and 0.17% was obtained, meeting the quality requirements for iron concentrate. The tailings from iron selection can be used as additives in cement and other construction materials. This integrated process combining pyrometallurgy and mineral processing enables the efficient and comprehensive utilization of blast furnace gas dust.
A novel single-scan hybrid 3D imaging method using Wave-CAIPI and MULTIPLEX technologies, named as WAMP, is proposed for 3D high-resolution rapid imaging. One single scan of the proposed rapid imaging method not only generates simultaneous B1t and T1 maps, but also qualitative images of T1W, PDW, T2*W, augmented T1W (aT1W), SWI and MRA, as well as parametric maps of T2* (R2*), PD and QSM. The in vivo experiments have showed that the proposed method could rapidly achieve high image quality and high quantification accuracy at the high acceleration factors in clinical applications.