Due to the inability of biochemical processes to remove refractory organic compounds from wastewater in pharmaceutical industrial parks, this research tried to find a new way to meet the requirement of the Discharge Standard in China. A combined process involving micro-electrolysis, Fenton oxidation, and coagulation was studied. Considering the removal efficiencies and operation costs, the reaction conditions were optimized. The COD concentration in the effluent after the combined treatment was less than the standard limit of 50 mg/L. Molecular weight distribution of organic compounds in wastewater was analyzed by sequential filtration and ultrafiltration. When treated by the combined process, the particulate fraction (particle size > 1,000 nm) decreased, and the soluble portion (particle size < 1 nm) increased significantly. Composition of the refractory organics was investigated using GC–MS. A total of 34 types of low-molecular-weight organics were identified in the effluent, among which phthalates, amides, heterocyclic compounds, and PAHs were the main organic pollutants. All these results show that the proposed method is promising for refractory wastewater because it is efficient and easy to operate.

In this study, an algal–bacterial symbiotic consortium was integrated with the sediment microbial fuel cell (SMFC) to construct an algal–bacterial cathode SMFC (AC-SMFC) for excess sewage sludge treatment and electricity generation. A bacterial cathode SMFC (BC-SMFC) and a static settling system (SS-system) were used as controls. Electrochemical analysis confirmed that the algal–bacterial biofilm on the cathode improved electricity production. The maximum power density of AC-SMFC was 75.21 mW/m², which was 65.70% higher than that of the BC-SMFC (45.39 mW/m²). After 60 days of treatment, AC-SMFC achieved much higher removal efficiencies of the total chemical oxygen demand (TCOD) (59.60%), suspended solids (SS) (62.42%), and volatile suspended solids (VSS) (71.44%) in the sediment, compared to BC-SMFC and the SS-system, exhibiting an effective degradation of the organic matter in the sediment sludge. Moreover, the lower concentration of total nitrogen (TN) and total phosphorus (TP) in the overlying water of AC-SMFC demonstrated that the algae on the cathode could inhibit the accumulation of nitrogen and phosphorus released from the sediments. The three-dimensional excitation–emission matrix (EEM) fluorescence spectroscopy revealed that the tryptophan protein and aromatic protein in the loosely bound extracellular polymeric substances (LB-EPS) of the sediment sludge in the AC-SMFC were significantly decreased. Additionally, the abundance of functional microbiota in the AC-SMFC increased, such as Trichococcus, Alphaproteobacteria, and Clostridia, which contributed to electricity generation and sludge degradation. The combined application of microalgae and the SMFC provided a promising approach for excess sludge reduction and energy recovery.

The high efficiency and low consumption green wastewater treatment technology has important practical significance for the recycling of printing and dyeing wastewater. The efficiency of visible light catalytic degradation of organics is greatly affected by the performance of the catalyst and the photo reactor. Therefore, Bi₂WO₆/TiO₂/Fe₃O₄ (mBT) visible light photocatalyst was accurately prepared by the ammonia iron double drop method. In order to improve the photodegradation efficiency, a tubular magnetic field-controlled photocatalytic reactor (MPR) was developed. The novel mBT-MPR visible light photocatalytic system was proposed to treat RhB simulated wastewater. The experimental results showed that when the dosage of mBT catalyst was 1 g/L and visible light was irradiated for 60 min, the average removal rate of rhodamine B (RhB) with initial an concentration of 10 mg/L in the simulated wastewater for four times was 91.7%. The mBT-MPR visible light photocatalysis system is a green and efficient treatment technology for organic pollutants in water with simple operation, low energy consumption, and no need for catalyst separation.