In the framework of wastewater treatment plants, sewage sludge can be directed to biochar production, which when coupled with an external iron source has the potential to be used as a carbon–iron composite material for treating various organic pollutants in advanced oxidation processes. In this research, “green” synthesized nano zero-valent iron (nZVI) supported on sewage sludge-based biochar (BC)–nZVI-BC was used in the Fenton process for the degradation of the recalcitrant organic molecule. In this way, the circular economy principles were supported within wastewater treatment with immediate loop closing; unlike previous papers, where only the water treatment was assessed, the authors proposed a new approach to wastewater treatment, combining solutions for both water and sludge. The following phases were implemented: synthesis and characterization of nano zero-valent iron supported on sewage sludge-based biochar (nZVI-BC); optimization of organic pollutant removal (Reactive Blue 4 as the model pollutant) by nZVI-BC in the Fenton process, using a Definitive Screening Design (DSD) model; reuse of the obtained Fenton sludge, as an additional catalytic material, under previously optimized conditions; and assessment of the exhausted Fenton sludge’s ability to be used as a source of nutrients. nZVI-BC was used in the Fenton treatment for the degradation of Reactive Blue 4—a model substance containing a complex and stable anthraquinone structure. The DSD model proposes a high dye-removal efficiency of 95.02% under the following optimal conditions: [RB4] = 50 mg/L, [nZVI] = 200 mg/L, [H₂O₂] = 10 mM. pH correction was not performed (pH = 3.2). Afterwards, the remaining Fenton sludge, which was thermally treated (named FS_treated), was applied as a heterogeneous catalyst under the same optimal conditions with a near-complete organic molecule degradation (99.56% ± 0.15). It could be clearly noticed that the cumulative amount of released nutrients significantly increased with the number of leaching experiments. The highest cumulative amounts of released K, Ca, Mg, Na, and P were therefore observed at the fifth leaching cycle (6.40, 1.66, 1.12, 0.62, 0.48 and 58.2 mg/g, respectively). According to the nutrient release and toxic metal content, FS_treated proved to be viable for agricultural applications; these findings illustrated that the “green” synthesis of nZVI-BC not only provides innovative and efficient Fenton catalysts, but also constitutes a novel approach for the utilization of sewage sludge, supporting overall process sustainability.

The main challenges to overcome within the Fenton process are the acidic pH as an optimal reaction condition, sludge formation in neutral pH medium and high toxicity of treated printing wastewater due to the generation of contaminating by-products. This research discusses catalytic activity of homogeneous (FeSO₄/H₂O₂) and heterogeneous (Fe₂(MoO₄)₃/H₂O₂) Fenton processes in treatment of Yellow azo printing dye in synthetic aqueous solution and real printing effluent, with an integration of adsorption on functionalized biochar synthesized from wild plum kernels. The definitive screening design (DSD), was used to design the experiment. Independent variables were initial dye concentration (20 - 180 mg L^-1), iron concentration (0.75 - 60 mg L^-1), pH (2 - 10) and hydrogen peroxide concentration (1 - 11 mM). Higher decolorization efficiency of 79% was obtained within homogeneous Fenton treatment of printing wastewater, in comparison to heterogeneous Fenton treatment (54%), after a reaction time of 60 min. Same trend of mineralisation degree was established: COD removal was 59% and 33% for homogeneous and heterogeneous Fenton process, respectively. The application of adsorption treatment has achieved significant advantages in terms of toxicity reduction (95%) and decolorization efficiency (90% of TOC removal and 22% of dye removal) of treated samples, even at neutral pH medium. Degradation mechanisms within Fenton and adsorption processes were proposed based on the qualitative gas chromatography/mass spectrometry analysis, physico-chemical properties of dye degradation products and functionalized biochar. Overall, the homogeneous Fenton/adsorption combined process can be potentially used as treatment to remove azo dyes from contaminated water.

Background: In past years, nanomaterials have been actively studied and developed and successfully used in many fields. Due to water scarcity, the application of nanomaterials in water and wastewater treatment has drawn significant attention. Due to their superior features, they represent functional materials with great potential for pollution removal and environmental applications. Objective: This literature review aims to summarize and present the metal nanoparticles used for dye wastewater treatment. The discussion subject is metallic nanoparticles for mentioned use, with a special focus on iron-based, bimetallic, and photocatalytic nanomaterials. Methods: Reference search of “metal nanoparticles in dye wastewater treatment” was conducted in detail through the Serbian Library Consortium for Coordinated Acquisition (KoBSON). Published papers search was mainly based on Web of Science and ScienceDirect database focusing on the latest research on this topic. The corresponding literature was carefully read, analyzed, and evaluated. Results: Two hundred and twenty-four scientific and review articles, thesis, and book chapters, patents were evaluated in order to summarise current trends in metal nanoparticle use in wastewater treatment. An increasing trend in scientific research regarding metal nanoparticles can be observed for the removal of different inorganic and organic pollutants. Among the most extensively tested are dye molecules, representing challenging species in terms of degradation and consequent removal. Modification, layering, combination, and green synthesis of metal nanoparticles result in materials capable of efficient and environmentally sustainable wastewater treatment. Conclusion: In this paper, extensive review of metal nanoparticles in dye wastewater treatment is presented. With rapid water demand, development of sustainable materials and technology is necessary. Use of these materials represents eco-friendly, energy efficient and sustainable water purification solution. However, matter of usage commercialization is still to be addressed.

Due to population growth and industrial development consumption of non-renewable energy sources, and consequently pollution, has increased. In order to reduce energy utilisation and preserve the environment, developed and developing countries are increasingly trying to find solutions based on renewable energy sources. Cost-effective wastewater treatment methods using solar energy would significantly ensure effective water source utilisation, thereby contributing towards sustainable development goals. In this paper, special emphasis is given to the use of solar energy as the driving force of the process, as well as the use of highly active magnetic TiO₂-based catalysts. Therefore, in this study, we investigated the possibility of photocatalytic degradation of aqueous magenta graphic dye using titanium dioxide as a catalyst and DSD model in order to achieve the best process optimisation. TiO₂ was successfully coated with magnetic nanoparticles by one step process and characterized using different techniques (BET, SEM/EDS, FTIR, XRD). Based on DSD statistical method optimal reaction conditions were pH = 6.5; dye concentration 100 mg/L; TiO₂–Fe₃O₄ 0.6 g/L, at which the highest degree of magenta dye decolourisation was achieved (85%). Application of solar energy coupled with magnetic TiO₂ catalyst which could be recovered and reused makes this approach a promising alternative in green wastewater treatment.

This research investigates the potential use of pyrite cinder (PC) as an efficient Fenton-like catalyst for the removal of the reactive azo dye Reactive Red 120 (RR120) from aqueous solutions. The characterization of its PC structure and composition confirmed its great potential to act as catalytic iron source in a heterogeneous Fenton system. Dye removal optimization was performed in terms of PC dosage (0.4–8 g/L), H₂O₂ concentration (2–25 mM), pH value (2–4.6), initial dye concentration (50–200 mg/L), and mixing time. The highest decolorization efficiency (92%) was achieved after a reaction time of 480 min under following conditions: RR120 = 50 mg/L, PC = 4 g/L, H₂O₂ = 10 mM, and pH = 3. After decolorization, an extensive analysis of the generated effluent was performed regarding metal leaching, mineralization, toxicity, and degradation product formation. The metal leaching indicated the necessity for a pH increase in order to remove the settled metal hydroxides. The mineralization efficiency was satisfactory, reaching 85% and 62% of the COD and TOC removal, respectively. The respirometry measurements and bioluminescence tests indicated the detoxification of the treated solution. The absorption spectra and GC/MS analysis confirmed the changes in the molecular structure in the form of the destruction of the azo bond, with a simpler aromatic and aliphatic intermediates formation. This study provides an effective method for removing azo dye in polluted water by employing waste tailings as alternative Fenton-like catalysts, while also using waste tailings as the secondary resource.