Here we show for the first time a MOF that is photocatalytically active for light-assisted CO₂methanation under mild conditions (215 °C), which can be further improved with the inclusion of metallic nanoparticles.

We have designed and synthesized eight isostructural 1D coordination polymers (CPs) with the general formula {[Ln(aapc)₃(DMF)]}_n [where Ln(III) = Y (2), La (3), Nd (4), Eu (5), Gd (6), Tb (7), Dy (8), Er (9); and aapc = 3-((anthraquinone-1-yl)amino)propanoate]. These CPs consist of Ln-carboxylate infinite rods in which the bulky anthraquinone scaffolds arise from it in such a way that the resulting supramolecular packing exhibits isolated 1D chains. Solution structures have been corroborated through NMR methods including PGSE and EXSY NMR studies and, due to the presence of lanthanide ions, magnetic and luminescence properties have been studied. Alternating current magnetic measurements of compound 8 show slow relaxation of the magnetization, a characteristic of single molecule magnets (SMMs). The evaluation of solid-state photophysical properties reveals that the aapc scaffold sensitizes lanthanide(III) based emission of compounds 4–9 both in the visible and near-infrared (NIR) regions at 10 K.

In this work, three isostructural metal-organic frameworks based on first row transition metal ions and 2-aminoisonicotinate (2ain) ligands, namely, {[M(μ-2ain)₂]·DMF}_n [M^II = Co (1), Ni (2), Zn (3)], are evaluated for their sensing capacity of various solvents and metal ions by monitoring the modulation of their magnetic and photoluminescence properties. The crystal structure consists of an open diamond-like topological 3D framework that leaves huge voids, which allows crystallizing two-fold interpenetrated architecture that still retains large porosity. Magnetic measurements performed on 1 reveal the occurrence of field-induced spin-glass behaviour characterized by a frequency-independent relaxation. Solvent-exchange experiments lead successfully to the replacement of lattice molecules by DMSO and MeOH, which, on its part, show dominating SIM behaviour with low blocking temperatures but substantially high energy barriers for the reversal of the magnetization. Photoluminescence studied at variable temperature on compound 3 show its capacity to provide bright blue emission under UV excitation, which proceeds through a ligand-centred charge transfer mechanism as confirmed by time-dependent DFT calculations. Turn-off and/or shift of the emission is observed for suspensions of 3 in different solvents and aqueous solutions containing metal ions.

Nanozymes are nanostructured artificial enzymes that have attracted great attention among researchers because of their ability to mimic relevant biological reactions carried out by their natural counterparts, but with the capability to overcome natural enzymes’ drawbacks such as low thermostability or narrow substrate scope. The promising enzyme-like properties of these systems make nanozymes excellent candidates for innovative solutions in different scientific fields such as analytical chemistry, catalysis or medicine. Thus, nanozymes with different type of activities are of special interest owing to their versatility since they can reproduce several biological reactions according to the substrates and the environmental conditions. In this context, gold-based nanozymes are a representative example of multifunctional structures that can perform a great number of enzyme-like activities. In addition, the combination of gold-based materials with structures of organic and inorganic chemical nature yields even more powerful hybrid nanozymes, which enhance their activity by providing improved features. This review will carry out a deep insight into gold-based nanozymes, revisiting not only the different type of biological enzymatic reactions that can be achieved with these kinds of systems, but also structural features of some of the most relevant hybrid gold-based nanozymes described in the literature. This literature review will also provide a representative picture of the potential of these structures to solve future technological challenges.