Nanofillers in resin materials can improve their mechanical and physicochemical properties. The present work investigated the effects of zirconia nanoparticles (NPs) as fillers in commercial dental luting cements. Two dual-cured self-adhesive composites and one resin modified glass ionomer (RMGI) luting cement were employed. Film thickness (FT), flexural strength (FS), water sorption (W_sp), and shear bond strength (SBS) to monolithic zirconia were evaluated according to ISO 16506:2017 and ISO 9917-2:2017, whereas polymerization progress was evaluated with FTIR. Photopolymerization resulted in double the values of DC%. The addition of 1% wt NPs does not significantly influence polymerization, however, greater amounts do not promote crosslinking. The sorption behavior and the mechanical performance of the composites were not affected, while the film thickness increased in all luting agents, within the acceptable limits. Thermocycling (TC) resulted in a deteriorating effect on all composites. The addition of NPs significantly improved the mechanical properties of the RMGI cement only, without negatively affecting the other cements. Adhesive primer increased the initial SBS significantly, however after TC, its application was only beneficial for RMGI. The MDP containing luting cement showed higher SBS compared to the RMGI and 4-META luting agents. Future commercial adhesives containing zirconia nanoparticles could provide cements with improved mechanical properties.

The purpose of the study was the investigation of the polymerization of a preheated composite resin beneath lithium disilicate. First, lithium disilicate discs in two shades (HT A2 and HT A4) and three different thicknesses (2, 4, and 6 mm) were bonded on dentine with preheated composite resin that was photo-polymerized for 20 s. The composite resin microhardness, the double bond conversion (DC) and their correlation were estimated. Second, standardized occlusal veneers of two shades and two different thicknesses (4 and 6 mm) were bonded with preheated composite resin and photopolymerized for 60 or 270 s. A microhardness line profiling was performed on the cross-section of each specimen and the correspondence DC was calculated. Shade and thickness of lithium disilicate were found to have a significant impact on micro-hardness and DC of the composite resin. Beneath standardized occlusal veneers DC can reach clinically acceptable level if photopolymerization duration is extended properly.

This study investigates the correlation between Amide I and III components in dentine’s infrared spectrum, focusing on structural changes due to acidic conditioning and adhesive treatments. Human dentine specimens (n=40) were treated with phosphoric acid, phytic acid, and two self-etching adhesives (G-Premio Bond and Adhese Universal), then analyzed using ATR-FTIR spectroscopy. Deconvolution of Amide I and III peaks quantified changes in secondary structures, including α-helices, β-sheets, and β-turns. Results showed strong positive correlations between specific Amide I and III components. The collagen triple helix remained stable after treatment, indicating its potential for normalizing Amide III components. Amide I, however, remains preferred for calculating the mineral-to-matrix ratio due to its higher intensity. The study highlights that Amide III analysis may be more accurate for monitoring structural changes in dentine collagen, avoiding errors from overlapping water vibrations with Amide I.