The integration of an increasing share of Renewable Energy Sources (RES) requires the availability of suitable energy storage systems to improve the grid flexibility and Compressed Air Energy Storage (CAES) systems could be a promising option. In this study, a CO₂-free Diabatic CAES system is proposed and analyzed. The plant configuration is derived from a down-scaled version of the McIntosh Diabatic CAES plant, where the natural gas is replaced with green hydrogen, produced on site by a Proton Exchange Membrane electrolyzer powered by a photovoltaic power plant. In this study, the components of the hydrogen production system are sized to maximize the self-consumption share of PV energy generation and the effect of the design parameters on the H₂-CAES plant performance are analyzed on a yearly basis. Moreover, a comparison between the use of natural gas and hydrogen in terms of energy consumption and CO₂ emissions is discussed. The results show that the proposed hydrogen fueled CAES can effectively match the generation profile and the yearly production of the natural gas fueled plant by using all the PV energy production, while producing zero CO₂ emissions.

The aim of this paper is to evaluate the overall life cycle environmental impact of an adiabatic compressed air energy storage (ACAES) system, which is designed to achieve the best match between the power production of a photovoltaic (PV) power plant and the power demand from the final user. The electrical energy demand of a small town, with a maximum power load of about 10 MW, is considered a case study. The ACAES system is designed with a compressor-rated power of about 10 MW and charging and discharging times of 10 and 24 h, respectively. Different sizes of the PV plant, ranging from 20 to 40 MWp, and two different solutions for the compressed air storage, an underground cavern, and a gas pipeline, are analyzed. The aim of this analysis is to compare the impacts on human health, ecosystem quality, climate change, and resource consumption of the PV power generation plant and the integrated PV-ACAES system with those of a reference scenario in which the end user demand is met entirely by the grid. The best results in terms of a reduction in environmental impact in comparison to the reference scenario are obtained for a small PV plant (20 MW) without the ACAES section, with reductions of about 85–95% depending on the category of impact. The integration of the ACAES system improves energy self-consumption but worsens the environmental impact, especially for air storage in gas pipelines. The best configuration in terms of environmental impact is based on a 30 MW PV plant integrated with an ACAES section using an underground cavern for air storage and allows for improvements in the energy self-consumption of between 38% and 61%, with a reduction in the environmental impact compared to the reference scenario of about 80–91% depending on the impact category.

In the transition to decarbonized energy systems, green ammonia will play a key role in reducing greenhouse gas emissions. However, its production remains an energy-intensive and economically demanding process. This study addresses these challenges by conducting a techno-economic optimization of a photovoltaic powered green ammonia production system, operating under grid curtailment conditions, with the aim of minimizing the levelized cost of ammonia. The system comprises a photovoltaic plant, a battery energy storage system, a proton exchange membrane water electrolyzer, a hydrogen storage unit, and a Haber-Bosch reactor for ammonia synthesis. A Mixed-Integer Linear Programming approach is employed to optimize component sizes and operation scheduling, with a target annual production of 1 kton of ammonia. Two curtailment scenarios are considered: one in which surplus electricity sold to the grid is valued at the Levelized Cost of Electricity, and an extreme scenario where surplus electricity has zero value. The analysis results in a levelized cost of ammonia of 1,038 €/ton, adjusted to 995 €/ton when considering electricity sales.

The integration of the increasing share of Renewable Energy Sources (RES) requires the availability of suitable energy storage systems to improve the grid flexibility, and Compressed Air Energy Storage (CAES) systems could be a promising option. In this study, a CO2-free Diabatic CAES system is proposed and analysed. The plant configuration is derived from a down-scaled version of the McIntosh diabatic CAES plant, where the natural gas is replaced with green hydrogen, produced on site by a Proton Exchange Membrane electrolyser powered by a Photovoltaic power plant. In this study, the components of the hydrogen production system are sized to maximize the Self-Consumption share of PV energy generation and the effect of the design parameters on the H2-CAES plant performance are analysed on a yearly basis. Moreover, a comparison between the use of natural gas and hydrogen in terms of energy consumption and CO2 emissions is discussed. The results show that the proposed hydrogen fuelled CAES can effectively match the generation profile and the yearly production of the natural gas fuelled plant by using all the PV energy production, while producing zero CO2 emissions.