Nanofluids, which consist of nanosized particles dispersed in a base fluid, represent a promising solution to improve the performance of thermal energy storage systems. This review offers a comprehensive overview of nanofluids and their applications in thermal energy storage systems, discussing their thermal properties, heat transfer mechanisms, synthesis techniques, and application in latent heat storage systems. Various types of nanofluids are examined, including metal oxide, carbon-based, and metallic nanofluids, highlighting their effects on thermal conductivity, latent heat and the phase change temperature. A review of experimental and numerical studies showcases the performance of thermal energy storage systems incorporating nanofluids and the factors influencing their thermophysical characteristics and energy storage capacity. Finally, the key findings of current research are summarized, as well as the challenges and the potential future directions in nanofluid-based thermal energy storage systems research, emphasizing the need to optimize nanoparticle concentration and long-term durability.
Despite the growing application of storage for curtailment mitigation, its cost-effectiveness remains uncertain. This study evaluates the Levelized Cost of Storage, which also represents an implicit threshold revenue, for Lithium-ion Battery Energy Storage Systems deployed for photovoltaic curtailment mitigation. Specifically, the LCOS is assessed—using a mathematical simulation model—for various curtailment scenarios defined by maximum levels (10–40%), hourly profiles (upper limit and proportional), and growth rates (2, 5, and 10 years) at three storage system capacities (0.33, 0.50, 0.67 h) and two European locations (Cagliari and Berlin). The results indicate that the LCOS of batteries deployed for curtailment mitigation is, on average, comparable to that of systems used for bulk energy storage applications (155–320 EUR/MWh) in Cagliari (180–410 EUR/MWh). In contrast, in Berlin, the lower and more variable photovoltaic generation results in significantly higher LCOS values (200–750 EUR/MWh). For both locations, the lowest LCOS values (180 EUR/MWh for Cagliari and 200 EUR/MWh for Berlin), obtained for very high curtailment levels (40%), are significantly above average electricity prices (108 EUR/MWh for Cagliari and 78 EUR/MWh for Berlin), suggesting that BESSs for curtailment mitigation are competitive in the day-ahead market only if their electricity is sold at a significantly higher price. This is particularly true for lower curtailment levels. Indeed, for a curtailment level of 10% reached in 5 years, the LCOS for a 0.5 h BESS capacity is approximately 255 EUR/MWh in Cagliari and 460 EUR/MWh in Berlin. The study further highlights that the curtailment scenario significantly affects the Levelized Cost of Storage, with the upper limit hourly profile being more conservative.
The integration of an increasing share of Renewable Energy Sources (RES) requires the availability of suitable energy storage systems to improve the grid flexibility and Compressed Air Energy Storage (CAES) systems could be a promising option. In this study, a CO2-free Diabatic CAES system is proposed and analyzed. The plant configuration is derived from a down-scaled version of the McIntosh Diabatic CAES plant, where the natural gas is replaced with green hydrogen, produced on site by a Proton Exchange Membrane electrolyzer powered by a photovoltaic power plant. In this study, the components of the hydrogen production system are sized to maximize the self-consumption share of PV energy generation and the effect of the design parameters on the H2-CAES plant performance are analyzed on a yearly basis. Moreover, a comparison between the use of natural gas and hydrogen in terms of energy consumption and CO2 emissions is discussed. The results show that the proposed hydrogen fueled CAES can effectively match the generation profile and the yearly production of the natural gas fueled plant by using all the PV energy production, while producing zero CO2 emissions.
In Concentrating Solar Power (CSP) systems, solar radiation allows to keep the Heat Transfer Fluid (HTF) at the design temperature (250-400°C using thermal oil) during daylight. During night, the thermal losses of the receiver tubes lead to a fast reduction of this temperature. The very first hours of daily solar irradiance are used to warm-up the Solar Field to the nominal temperature. This work focuses on a detailed analysis of the thermal losses of a 8,400 m2 Solar Field based on Linear Fresnel Collectors (LFC) using thermal oil as Heat Transfer Fluid. The proposed simulation model evaluates the performance of the Solar Field as a function of solar radiation, solar position, ambient temperature and wind speed for given values of the main geometrical and technical characteristics of the SF components (insulated piping and solar receivers), as well as for assigned thermodynamic properties of the Heat Transfer Fluid. The time-step considered (1 second) and the dense spatial discretization chosen allow the energy-balance-equation-based model to be suited to simulate night, warm-up and full-operation phases