Due to its extremely high theoretical mass specific capacity, silicon is considered to be the most promising anode material for lithium-ion batteries (LIBs). However, serious volume expansion and poor conductivity limit its commercial application. Herein, dealloying treatments of spray dryed Al-Si-Cu-Ni particles are performed to obtain a Cu/Ni co-doped Si-based anode material with a porous nanowire network structure. The porous structure enables the material to adapt to the volume changes in the cycle process. Moreover, the density functional theory (DFT) calculations show that the co-doping of Cu and Ni can improve the capture ability towards Li, which can accelerate the electron migration rate of the material. Based on the above advantages, the as-prepared material presents excellent electrochemical performance, delivering a reversible capacity of 1092.4 mAh g⁻¹ after 100 cycles at 100 mA g⁻¹. Even after 500 cycles, it still retains 818.7 mAh g⁻¹ at 500 mA g⁻¹. This study is expected to provide ideas for the preparation and optimization of Si-based anodes with good electrochemical performance.

As high-capacity anode materials, spinel NiFe₂O₄ aroused extensive attention due to its natural abundance and safe working voltage. For widespread commercialization, some drawbacks, such as rapid capacity fading and poor reversibility due to large volume variation and inferior conductivity, urgently require amelioration. In this work, NiFe₂O₄/NiO composites with a dual-network structure were fabricated by a simple dealloying method. Benefiting from the dual-network structure and composed of nanosheet networks and ligament-pore networks, this material provides sufficient space for volume expansion and is able to boost the rapid transfer of electrons and Li ions. As a result, the material exhibits excellent electrochemical performance, retaining 756.9 mAh g⁻¹ at 200 mA g⁻¹ after cycling for 100 cycles and retaining 641.1 mAh g⁻¹ after 1000 cycles at 500 mA g⁻¹. This work provides a facile way to prepare a novel dual-network structured spinel oxide material, which can promote the development of oxide anodes and also dealloying techniques in broad fields.