The propagation of surface acoustic waves (SAWs) along a ZnO/SiO₂/Si piezoelectric structure is experimentally and theoretically studied. Six surface acoustic modes were experimentally detected in the 134 to 570 MHz frequency range, for acoustic wavelength λ = 30 μm, and for SiO₂ and ZnO layers with a thickness of 1 and 2.4 μm. The numerical and three-dimensional (3D) finite element method analysis revealed that the multilayered substrate supports the propagation of Rayleigh and Sezawa modes (R_m and S_m), their third and fifth harmonics at λ/3 and λ/5. The velocity of all the modes was found in good agreement with the theoretically predicted values. Eigenfrequency, frequency domain, and time domain studies were performed to calculate the velocity, the electroacoustic coupling coefficient, the shape of the modes, the propagation loss, and the scattering parameter S₂₁ of the SAW delay lines based on the propagation of these modes. The sensitivity to five different gases (dichloromethane, trichloromethane, carbontetrachloride, tetrachloroethylene, and trichloroethylene) was calculated under the hypothesis that the ZnO surface is covered by a polyisobutylene (PIB) layer 0.8 µm thick. The results show that the modes resonating at different frequencies exhibit different sensitivities toward the same gas. The multi-frequency ZnO/SiO₂/Si single device structure is a promising solution for the development of a multiparameters sensing platform; multiple excitation frequencies with different sensing properties can allow the parallel analysis of the same gas with improved accuracy.

Finite element analysis is carried out to investigate the characteristics of Rayleigh, Sezawa and Love surface acoustic modes travelling along c-axis tilted ZnO layer on Si (001) half-space. The phase velocity dispersion curves, electromechanical coupling, reflectivity and mass loading sensitivity are studied for different electroacoustic coupling configurations and c-axis tilt angles θ. The behavior of Rayleigh and Sezawa modes operating as gas sensor, was simulated under the hypothesis that the ZnO free surface is covered with a thin polyisobutylene (PIB) film, 0.2 μm thick, able to selectively adsorb volatile gases at atmospheric pressure and room temperature. The sensor sensitivity to gas concentration in air, i.e. the frequency shifts per unit gas concentration, is studied and compared to some common materials used in literature. The obtained results, demonstrate the feasibility of high-frequency multimode micro-sensor based on the c-axis tilted ZnO piezoelectric thin film and operating in both liquid and gaseous environments.

Piezoelectric c-axis oriented zinc oxide (ZnO) thin films, from 1.8 up to 6.6 µm thick, have been grown by the radio frequency magnetron sputtering technique onto fused silica substrates. A delay line consisting of two interdigital transducers (IDTs) with wavelength λ = 80 µm was photolithographically implemented onto the surface of the ZnO layers. Due to the IDTs’ split-finger configuration and metallization ratio (0.5), the propagation of the fundamental, third, and ninth harmonic Rayleigh waves is excited; also, three leaky surface acoustic waves (SAWs) were detected travelling at a velocity close to that of the longitudinal bulk wave in SiO₂. The acoustic waves’ propagation in ZnO/fused silica was simulated by using the 2D finite-element method (FEM) technique to identify the nature of the experimentally detected waves. It turned out that, in addition to the fundamental and harmonic Rayleigh waves, high-frequency leaky surface waves are also excited by the harmonic wavelengths; such modes are identified as Sezawa waves under the cut-off, hereafter named leaky Sezawa (LS). The velocities of all the modes was found to be in good agreement with the theoretically calculated values. The existence of a low-loss region in the attenuation vs. layer thickness curve for the Sezawa wave below the cut-off was theoretically predicted and experimentally assessed.

Using the finite element method, we have studied the Lamb modes characteristics propagation in c‑tilted ZnO/SiC thin film composite membrane. Phase velocity dispersion curves,...