Magnesium oxide (MgO) has been investigated as a wet mineral carbonation adsorbent due to its relatively low adsorption and regeneration temperatures. The carbon dioxide (CO₂) capture efficiency can be enhanced by applying external force on the MgO slurry during wet carbonation. In this study, two aerosol-processed MgO nanoparticles were tested with a commercial MgO one to investigate the external force effect on the wet carbonation performance at room temperature. The MgO nano-adsorbents were carbonated and sampled every 2 h up to 12 h through forced and non-forced wet carbonations. Hydrated magnesium carbonates (nesquehonite, artinite and hydromagnesite) were formed with magnesite through both wet carbonations. The analyzed results for the time-dependent chemical compositions and physical shapes of the carbonation products consistently showed the enhancement of wet carbonation by the external force, which was at least 4 h faster than the non-forced carbonation. In addition, the CO₂ adsorption was enhanced by the forced carbonation, resulting in a higher amount of CO₂ being adsorbed by MgO nanoparticles than the non-forced carbonation, unless the carbonation processes were completed. The adsorbed amount of CO₂ was between the maximum theoretical amounts of CO₂ adsorbed by nesquehonite and hydromagnesite.

This study investigates the carbon dioxide (CO₂) emission characteristics of using torrefied biomass (residual wood and wood chip) as co-firing materials in coal-fired power plants, based on life cycle assessment techniques. We quantify the greenhouse gas (GHG) mitigation potential of substituting coal with biomass under different torrefaction temperatures, biomass types, and co-firing ratios. Results indicate that higher co-firing ratios significantly reduce CO₂ emissions. Torrefaction at 270 °C was identified as optimal, balancing high energy yield and minimized emissions, while 310 °C torrefaction showed limited mitigation benefits due to lower mass yields and higher carbon content. Pelletization and torrefaction enhanced biomass properties, but the energy intensity of these processes affected the overall emission balance. This study underscores the potential of biomass to replace imported coal and contribute to carbon neutrality, while highlighting the importance of optimizing biomass processing conditions. Future work should focus on refining torrefaction parameters and assessing other biomass characteristics to enhance operational efficiency in coal-fired power plants.

Airborne molecular contamination (AMC) represents a wide range of gaseous contaminants in the cleanroom air environment. It is difficult to monitor AMC in the cleanroom air using conventional methods in real-time due to its ultra-low concentrations, such as part-per-billion or -trillion (ppb or ppt). In this study, AMC in the real university cleanroom air environment was investigated to figure out hot spots through portable soft X-ray radiolysis detector, which converts gaseous AMC into nanoparticles (gas-to-particle conversion) under the soft X-ray irradiation. A soft X-ray was connected to a clean stainless steel chamber to convert the introduced AMC into nanoparticles, and the size distributions of nanoparticles were measured through a scanning mobility particle sizer, which consists of a differential mobility analyzer and a condensation particle counter. By converting the size distribution information into total particle volume concentrations, equivalent AMC concentrations can be calculated using an appropriate calibration curve between AMC and the total particle volume concentration. The volume concentration of nanoparticles were converted into an equivalent sulfur dioxide (SO₂, a major acidic AMC in the cleanroom air) concentration by a calibration curve between SO₂ and the particle volume concentrations. AMC levels at different locations in the cleanroom at the University of Minnesota were measured by the soft X-ray-assisted AMC detector, and revealed that several tenth-order of pptV (lower than 15 pptV) in terms of the equivalent SO₂ concentration existed in the cleanroom air environment.

This study investigates the adsorption performance of biochar synthesized under varying pyrolysis and CO₂ activation conditions for the simultaneous removal of nitrogen monoxide (NO) and sulfur dioxide (SO₂), with an additional focus on its environmental impacts via life cycle assessment (LCA). Biochar was produced from Hinoki cypress using a two-stage process comprising initial pyrolysis followed by CO₂ activation, and its physicochemical properties were evaluated through pore structure analysis. Adsorption experiments were conducted under both single- and combined-gas conditions to assess the synergistic or competitive behaviors of NO and SO₂ adsorption. The results indicated that activation conditions significantly influenced the surface area and pore volume of biochar, leading to enhanced gas adsorption capacities. A trade-off between biochar yield and pollutant removal efficiency was observed, suggesting an optimal activation temperature balancing these two factors. Furthermore, the LCA approach, employing IPCC 2021 GWP 100 metrics, quantified the environmental impacts of biochar production under different thermal conditions. The findings revealed that although higher activation temperatures improved adsorption efficiency, they also resulted in increased energy consumption and associated greenhouse gas emissions. These outcomes demonstrate the necessity of optimizing activation parameters not only for functional performance but also for environmental sustainability. This work provides insight into designing efficient biochar-based gas treatment systems and supports their potential application as eco-friendly alternatives in industrial emission control strategies.