In recent years, porous titanium (Ti) scaffolds with BaTiO₃ coatings have been designed to promote bone regeneration. However, the phase transitions of BaTiO₃ have been understudied, and their coatings have yielded low effective piezoelectric coefficients (EPCs < 1 pm/V). In addition, piezoelectric nanomaterials bring many advantages in eliciting cell-specific responses. However, no study has attempted to design a nanostructured BaTiO₃ coating with high EPCs. Herein, nanoparticulate tetragonal phase BaTiO₃ coatings with cube-like nanoparticles but different effective piezoelectric coefficients were fabricated via anodization combining two hydrothermal processes. The effects of nanostructure-mediated piezoelectricity on the spreading, proliferation, and osteogenic differentiation of human jaw bone marrow mesenchymal stem cells (hJBMSCs) were explored. We found that the nanostructured tetragonal BaTiO₃ coatings exhibited good biocompatibility and an EPC-dependent inhibitory effect on hJBMSC proliferation. The nanostructured tetragonal BaTiO₃ coatings of relatively smaller EPCs (<10 pm/V) exhibited hJBMSC elongation and reorientation, broad lamellipodia extension, strong intercellular connection and osteogenic differentiation enhancement. Overall, the improved hJBMSC characteristics make the nanostructured tetragonal BaTiO₃ coatings promising for application on implant surfaces to promote osseointegration.

Barium titanate (BaTiO₃) is a typical perovskite-type oxide with high dielectric constant, low dielectric loss, and excellent ferroelectric, piezoelectric, pyroelectric, and other properties. In view of the low photogenerated electron-hole separation efficiency of T-BT itself, it is proposed to prepare nanocomposites with good catalytic performance by compound modification with Ag. Considering repeated use, on the basis of powder catalysis, a porous block is prepared by compounding powder and organic polymer PVDF. In this study, the t-BaTiO₃/Ag/β-PVDF composite material with porosity of ∼70.4% was prepared with the raw material of PVDF and piezoelectric t-BaTiO₃/Ag. The mechanical and piezoelectric photocatalytic properties of the composite material was studied systematically. The piezoelectric coefficient d ₃₃ is 1.44 pC/N which can be explained by COMSOL simulation calculation. Moreover, the compressive strength is 1.76 MPa. The degradation MO and RhB results indicated that t-BaTiO₃/Ag/β-PVDF composite material had good degradation and cycle stability.

Some photosensitive resins have poor mechanical properties after 3D printing. To overcome these limitations, a polyurethane acrylate oligomer (PUA) microsphere was prepared using the Pickering emulsion template method and ultraviolet (UV) curing technology in this paper. The prepared PUA microspheres were added to PUA-1,6-hexanediol diacrylate (HDDA) photosensitive resin system for digital light processing (DLP) 3D printing technology. The preparation process of PUA microspheres was discussed based on micromorphology, and it was found that the oil-water ratio of the Pickering emulsion and the emulsification speed had a certain effect on the microsphere size. As the oil-water ratio and the emulsification speed increased, the microsphere particle size decreased to a certain extent. Adding a suitable proportion of PUA microspheres to the photosensitive resin can improve the mechanical properties and thermal stability. When the modified photosensitive resin microsphere content was 0.5%, the tensile strength, elongation at break, bending strength, and initial thermal decomposition temperature were increased by 79.14%, 47.26%, 26.69%, and 10.65%, respectively, compared with the unmodified photosensitive resin. This study provides a new way to improve the mechanical properties of photosensitive resin 3D printing. The resin materials studied in this work have potential application value in the fields of ceramic 3D printing and dental temporary replacement materials.

This study explores a novel technique of preparing porous ceramics using egg white protein foaming method, in which hydrophobically modified Al₂O₃ particles self-assembly on the surface of protein bubbles to form a stable foam slurry, which is ultimately discharged and sintered to make porous Al₂O₃ ceramics. And egg white protein was a non-toxic and harmless natural substance that functions simultaneously as a foaming agent, a binder, and a gelling agent, has a significant advantage over ordinary foaming agents. The effect of protein foam content on the microscopic morphology, pore distribution, and strength of the porous ceramics was investigated. The mechanism of porous ceramics prepared by the protein foaming method was analyzed and the reliability of the study was verified by simulating the possible bonding with Gaussian 6.0. Porous ceramics with open porosity of 11.2–38.82%, near-spherical shape, average pore size of 150–240 μm, and compressive strength of 84–140 MPa were fabricated. The thermal insulating results showed that the porous ceramics have good thermal insulation performance, which was expected to be applied in the fields of aviation heat shields.