Fire extinguishing with the superior performance of fly ash composite colloid material is a cost‐effective colloid fire prevention technology. In this paper, a new powder additive (suspending agent (XK‐XJ) and gelling agent) was developed for the existing fire extinguishing technology of fly ash compound colloid. Tests show that the best additions to the fly ash slurry were 0.3% and 0.1∼0.3%, respectively. The grouting technical scheme of adding a suspending agent on the ground and gelling agent downhole was proposed to solve the problems of solid material settlement and blockage in the long‐distance pipeline transportation process. Finally, the optimized fly ash colloid fire prevention and extinguishing technology was successfully applied to the fire control engineering examples of close‐range coal seam groups, and the rationality of the developed powder and its proportion was tested, and the feasibility in coal fire control was tested.

High-temperature poisonous smoke produced by coal mine roadway fire seriously affects miners' lives and safety. Studying the development law of high-temperature smoke in the process of mine roadway fire and then exploring the danger of roadway are of great significance to personnel safety and post-disaster rescue. In order to study this problem, the CFD numerical simulation method is used to establish a fire calculation model based on ANSYS Fluent software in the development stage of mine fire. The high-temperature flue gas flow in the roadway during the development stage of mine fire is simulated, and the variation law of temperature field and gas concentration field with time and space position under different levels of roadway in the development stage of fire is revealed. The variation rules of environmental parameters, such as temperature, CO, and CO₂, are obtained by numerical calculation. Based on these, the danger zones of smoke spread in fire development stage are divided by the critical values of high-temperature smoke and toxicity evaluation index, and the mathematical fitting analysis of the evolution of the dangerous area with time is carried out. The research results have certain theoretical guiding significance for reducing underground environmental pollution and ensuring the personal safety of workers and rescuers.