Residual wall thickness is an important indicator for water-assisted injection molding (WAIM) parts, especially the maximization of hollowed core ratio and minimization of wall thickness difference which are significant optimization objectives. Residual wall thickness was calculated by the computational fluid dynamics (CFD) method. The response surface methodology (RSM) model, radial basis function (RBF) neural network, and Kriging model were employed to map the relationship between process parameters and hollowed core ratio, and wall thickness difference. Based on the comparison assessments of the three surrogate models, multiobjective optimization of hollowed core ratio and wall thickness difference for cooling water pipe by integrating design of experiment (DOE) of optimized Latin hypercubes (Opt LHS), RBF neural network, and particle swarm optimization (PSO) algorithm was studied. The research results showed that short shot size, water pressure, and melt temperature were the most important process parameters affecting hollowed core ratio, while the effects of delay time and mold temperature were little. By the confirmation experiments for the best solution resulted from the Pareto frontier, the relative errors of hollowed core ratio and wall thickness are 2.2% and 3.0%, respectively. It demonstrated that the proposed hybrid optimization methodology could increase hollowed core ratio and decrease wall thickness difference during the WAIM process.

Conductive multi-walled carbon nanotubes (MWCNTs) as well as piezoelectric zinc oxide (ZnO) nanoparticles are frequently used as a single additive and dispersed in polyvinylidene fluoride (PVDF) solutions for the fabrication of piezoelectric composite films. In this study, MWCNT/ZnO binary dispersions are used as spinning liquids to fabricate composite nanofibrous films by electrospinning. Binary additives are conducive to increasing the crystallinity, piezoelectric voltage coefficient, and consequent piezoelectricity of as-spun films owing to the stretch-enhanced polarization of the electrospinning process under an applied electric field. PCZ–1.5 film (10 wt. % PVDF/0.1 wt. % MWCNTs/1.5 wt. % ZnO nanoparticles) contains the maximum β-phase content of 79.0% and the highest crystallinity of 87.9% in nanofibers. A sensor using a PCZ–1.5 film as a functional layer generates an open-circuit voltage of 10 V as it is subjected to impact loads with an amplitude of 6 mm at 10 Hz. The piezoelectric sensor reaches a power density of 0.33 μW/cm² and a force sensitivity of 582 mV/N. In addition, the sensor is successfully applied to test irregular motions of a bending finger and stepping foot. The result indicates that electrospun PVDF/MWCNT/ZnO nanofibrous films are suitable for wearable devices.

Typical extension flow occurs in electrospinning process of Poly(vinylidene fluoride) (PVDF) solutions such that researchers focus on extensional rheological behaviors of PVDF solutions. The extensional viscosity of PVDF solutions is measured to know the fluidic deformation in extension flows. The solutions are prepared by dissolving PVDF powder into N,N-dimethylformamide (DMF) solvent. A homemade extensional viscometric device is used to produce uniaxial extension flows and the feasibility of the viscometric device is verified by applying the glycerol as a test fluid. Experimental results show that PVDF/DMF solutions are extension shinning as well as shear shinning. The Trouton ratio of thinning PVDF/DMF solution is close to three at very low strain rate and then reaches a peak value until it drops to a small value at high strain rate. Furthermore, an exponential model may be used to fit the measured values of uniaxial extensional viscosity at various extension rates, while traditional power-law model is applicable to steady shear viscosity. For 10~14% PVDF/DMF solution, the zero-extension viscosity by fitting reaches 31.88~157.53 Pa·s and the peak Trouton ratio is 4.17~5.16 at applied extension rate of less than 34 s⁻¹. Characteristic relaxation time is λ~100 ms and corresponding critical extension rate is ${\dot{\epsilon }}_c$~5 s⁻¹. The extensional viscosity of very dilute PVDF/DMF solution at very high extension rate is beyond the limit of our homemade extensional viscometric device. This case needs a higher sensitive tensile gauge and a higher-accelerated motion mechanism for test.