This study investigated the different thicknesses of TiO₂ photoanode films and the effect of surface plasmon resonance (SPR) of Ag-TiO₂ nanocomposites on the current-voltage (I–V) performance of dye-sensitized solar cells (DSSC). The TiO₂ layer was deposited using the doctor blade technique and the thickness of the TiO₂ films was controlled by using a different number of Scotch tape layers. The silver nanoparticles (AgNP) were synthesised using a chemical reduction method and the concentration of sodium citrate as a reducing agent was varied from 4 to 12 mM to study the effect of citrate ion on the size of the nanoparticles. Ag-TiO₂ nanopowder was prepared by adding pure anatase TiO₂ powder into AgNP colloidal solution. The mixture was left to dry for 24 h to obtain Ag-TiO₂ powder for paste preparation. The three-layer Scotch tape, with thickness of 14.38 µm, achieved a high efficiency of 4.14%. This results showed that three layers was the optimal thickness to improve dye loading and to reduce the charge recombination rate. As for the Ag-TiO₂ nanocomposites, 10 mM of AgNP, with a mean diameter of 65.23 nm and high efficiency of 6.92%, proved that SPR can enhance the absorption capability of dye and improve the photon-to-electron generation.

The design and development of sensitizing dyes possessing wide-wavelength photon harvesting encompassing visible to near-infrared (NIR) wavelength regions are unavoidable for increasing the overall efficiency of dye-sensitized solar cells (DSSCs). In this study, three far-red-sensitive squaraine sensitizers were designed computationally, synthesized, and characterized, aiming towards their suitability as a potential sensitizer for DSSCs. It has been found that the incorporation of an electron acceptor moiety in the central squaraine core brought about a red shift in the absorption maximum (λ_max) and the emergence of a secondary absorption band in the blue region, thus broadening the photon-harvesting window. In addition, it also lowered the dye’s HOMO energy level enabling a facile regeneration of the photo-excited dye, which improved the photovoltaic performance of SQ-223, exhibiting a photoconversion efficiency (PCE) of 4.67%. Thereafter, to address the issue of wide-wavelength photon harvesting, DSSCs were fabricated by co-adsorbing two complementary dyes SQ-223 and D-131 in various molar ratios. The DSSC fabricated with D-131 and SQ-223 in 9:1 molar ratio displayed the best photovoltaic performance with a PCE of 5.81%, a significantly higher PCE when compared to corresponding individual dye-based DSSCs containing D-131 (3.94%) and SQ-223 (4.67%).

Bifacial dye-sensitized solar cells (DSSCs) were fabricated utilizing dye cocktails of two dyes, Z-907 and SQ-140, which have complementary light absorption and photon harvesting in the visible and near-infrared wavelength regions, for panchromatic photon harvesting. The investigation of the rate of dye adsorption and the binding strengths of the dyes on mesoporous TiO₂ corroborated the finding that the Z-907 dye showed a rate of dye adsorption that was about >15 times slower and a binding that was about 3 times stronger on mesoporous TiO₂ as compared to SQ-140. Utilizing the dye cocktails Z-907 and SQ-140 from ethanol, the formation of the dye bilayer, which was significantly influenced by the ratio of dyes and adsorption time, was demonstrated. It was demonstrated that the dyes of Z-907 and SQ-140 prepared in 1:9 or 9:1 molar ratios favoured the dye bilayer formation by subtly controlling the adsorption time. In contrast, the 1:1 ratio counterpart was prone to form mixed dye adsorption; the best performance of the BF-DSSCs was shown when a dye cocktail of Z-907 and SQ-140 in a molar 9:1 ratio was used to prepare a photoanode for 1 h of dye adsorption. The BF-DSSCs thus exhibited PCEs of 4.23% and 3.48% upon the front and rear side light illuminations, a cumulated PCE of 7.71%, and a very good BBF of 83%.

Bifacial solar cells are gaining popularity due to their compactness, space‐saving property, and higher photoconversion efficiency (PCE) than mono‐facial solar cells. Bifacial dye‐sensitized solar cells (BF‐DSSCs) are fabricated and characterized utilizing D‐205 as a dye sensitizer in combination with I⁻/I₃⁻ and Co²⁺/Co³⁺ redox electrolytes. BF‐DSSCs using iodine‐based electrolytes demonstrate a cumulative PCE and bifaciality factor (BFF) of 13.05% and 85%, respectively. The hampered PCE under backside light illumination is attributed to the absorption of photons by the electrolyte itself. Contrary to this, BF‐DSSCs fabricated using cobalt‐complex‐based redox electrolyte exhibits an exceptionally high BFF of nearly 100% with a PCE of 4.77% and 4.75% under the front‐ and rear‐light illumination, respectively. Although the open‐circuit voltage of the BF‐DSSCs fabricated using cobalt electrolyte (with deeper redox potential) is slightly higher than that of BF‐DSSCs fabricated using iodine electrolyte, their cumulative PCE (9.52%) is much lower than that of iodine‐based device counterparts (13.05%). This decrease in PCE is attributed to the relatively fast charge recombination in the cobalt‐electrolyte‐based BF‐DSSCs.

Dye-sensitized solar cells (DSSCs) with the capability of photon harvesting from both front and rear sides, consisting of newly developed NIR dye (SQ-140), iodine-based redox electrolyte, and transparent counter electrode with high bifaciality factor (BFF) and good cumulated photoconversion efficiency (PCE), are successfully fabricated and characterized. The use of transparent TiO ₂ -based photoanode leads to improved BFF as compared to its opaque TiO ₂ counterparts: from 74% to 86% under similar experimental conditions and device parameters. The high molar extinction coefficient of the NIR dye SQ-140, needing a thinner TiO ₂ layer, was found to be advantageous to maintaining the high BFF even in thicker TiO ₂ films without serious compromise in the PCE. The lower efficiency of the bifacial DSSC under rear illumination was attributed to the hampered optical penetration as well as absorption of light by the intense colored iodine-based redox electrolyte.

The thickness of the photoanode film in dye-sensitized solar cells (DSSC) is a crucial parameter for optimum power conversion efficiency. The thick film can provide a high generation rate of a free electron, and at the same time, the charge recombination of electrons also increases. Therefore, there is competition between electron generation and charge recombination, which can cause the decreased performance of the DSSC. Meanwhile, the thinner film can reduce the charge recombination, but the dye loading on titanium dioxide (TiO2) will be low, which also can downgrade the DSSC performance. Therefore, optimised thickness from the current-voltage characteristic to understand the effect of thickness on efficiency and photocurrent generation. The result shows that the optimum thickness is 3 layers of scotch tape with short-circuit current density and efficiency of 10.96 mA/cm2 and 3.81 %.