The recent progress and major challenges/opportunities of MOF-derived hollow materials for energy storage are summarized in this review, particularly for lithium-ion batteries, sodium-ion batteries, lithium–Se batteries, lithium–sulfur batteries and supercapacitor applications.

Recently, transition metal chalcogenides, particularly molybdenum chalcogenides, have triggered intensive interest due to their intriguing physicochemical properties. Owing to its high anisotropy and distinct crystal structure, numerous reports have demonstrated that nanostructured MoS₂, with the merits of low cost and prominent properties, is an excellent substitute for environmentally benign energy conversion and for use in storage devices. Its different compounds, such as MoS₂/carbon, MoS₂/polymer, and MoS₂/metal oxides, have also been applied in the field of energy storage, including supercapacitors and batteries. In this review, we summarize the most recent advances made in the last 5 years in the development of MoS₂ and MoS₂-based composites in various electrochemical domains. In the discussion, emphasis is given to applications in supercapacitors, lithium-ion batteries, and sodium-ion batteries. Finally, some further prospects and promising developments of the materials in the energy storage field are proposed.