The black soldier fly (BSF) Hermetia Illucens can grow rapidly and on a wide variety of organic materials, and it is extensively used as a means of disposing of household organic waste. Different phases of the life cycle of BSF larvae (BSFL) are used in this work to extract chitin after the removal of lipids, mineral salts, and proteins. Multiple techniques, such as X-ray diffractometry, infrared spectroscopy, solid-state Nuclear Magnetic Resonance (¹³C ss-NMR) and thermogravimetric analysis, are used to investigate the chemical and physical characteristics of the extracted samples of chitin, which shows a high degree of acetylation (from 78% to 94%). The extracted chitin shows an increase of the thermal stability of 20 °C in the initial stage of life and 35 °C at the end of the life cycle if compared with a commercial standard. Moreover, the extracted chitin shows an increase in the crystallinity degree during the BSFL growth time (from 72% to 78%).

Recently, different methods have been proposed to develop wood materials, termed “densified woods”, with density increment and improvement in mechanical proprieties. Almost all the proposed methods involve the use of reducing agents and strong bases. In this work, a new method has been developed involving the use of less polluting agents. The formation of densified woods is divided into two steps: delignification involves the removal of lignin, hemicelluloses, and shorter chains of cellulose, whereas densification involves the plastering of the delignified woods. The obtained materials showed a density increase of two to four times. The obtained densified woods were characterized by spectroscopic, microscopic, and thermogravimetric techniques and mechanical tests. The characterizations aimed at determining the variations of chemical and structural compositions of the samples after delignification and densification processes, showing, respectively, a decrease in lignin and a significant increase in the density and force necessary to bring the materials to yield. The final density of wood was two to three times higher and the force necessary to reach the yield point reached more than three times the initial one for some of the studied samples. These characterizations showed how different woods, with different properties, reach comparable densities and final mechanical properties after delignification and densification process. The increased mechanical properties of the materials allow their application in place of other composite woody materials.

In the last few years, the role of science in Cultural Heritage has assumed greater significance since diagnostics have become essential for the characterization of artworks. The development of conservation strategies involves growing the study of artworks and the knowledge of the materials used against the degradation plaguing the painted surfaces. This work focuses on the investigation of the degradation processes involving paintings on canvas, in particular delamination and progressive deterioration of the painted surfaces. The main causes of the degradation are attributable to the formation of metal soaps, which originate from the interaction between binders and pigments; as a result, the process leads to the progressive fracturing of the paint film. Using various characterization techniques allowed us to acquire information on the structural and morphological properties of the binder resins and study the binder/pigment interaction during the degradation process to understand the quantity and quality of the acid sites present in the binders and, consequently, the potential reactivity with the cationic part of the pigments. The binders were also analyzed within paint layers in contact with zinc oxide to study the interactions and the possible formation of new species as metal soaps and metal oxalates that can modify the boundary among the painting layers and, consequently, the appearance of the artwork and its artistic value. Modifications after UV and thermal aging processes were observed using Infrared spectroscopy and thermogravimetric analysis. Zinc soap formation was observed after 7 h of a UV aging process and was correlated to the acidity of the resins.

In recent decades, fabric-dyeing processes involved greener processes because, since ancient times, dyers used mordants based on metals to make the color better adhere to the textile fibers, but this is the reason for their increased pollution. To develop new strategies, attention was focused on finding the best condition for a dyeing method for natural fibers of vegetable and animal origin (cotton and wool) using an ancient natural dye known as folium. Folium was used mostly in miniature painting in an attempt to avoid the use of classical mordants and solvents. To this purpose, plasma treatment and chitosan coating were employed. Firstly, the textile fibers were analyzed through infrared spectroscopies to verify surface modifications; subsequently, the post-treatment morphological variations were observed via scanning electron microscopy. Both techniques highlighted a significant variation of the surface functional groups due to plasma treatments with He-O₂ mixtures, which allowed a greater adhesion of chitosan on the fiber’s surface. Finally, the color strength of samples dyed with folium was tested through fiber optic reflectance spectroscopy, and the folium absorbance peaks were still detected after fabric washing. It is thus shown how an ancient, traditional raw matter has become relevant for developing new modern technologies.

In recent decades, pollution from dyes has increasingly attracted the attention of researchers. For this reason, the development of new materials capable of sequestering this type of pollutant has been extensively studied, especially as research using plant biomass to produce new materials. Considerable attention has been directed toward bamboo moso, which has been the focus of extensive studies. The chemical composition of bamboo culms indicates that cellulose and hemicellulose comprise 65–70%, whereas lignin accounts for 18–30%. In this study, lignin has been extracted from bamboo culms using the hydrothermal methodology under basic conditions. Water-soluble lignin was dispersed in a porogenic organic solvent and polymerized via the Friedel-Craft alkylation reaction. ¹³C CPMAS NMR spectroscopy was used to study the modification of the water-soluble lignin before and after polymerization; the peaks related to the linker reaction were detected and confirmed the successful cross-linking reaction. The biopolymer-composite was also characterized by FTIR spectroscopy to explore the surface functionality and its interaction with the aromatic molecules, using toluene as a model compound. To gain a deeper understanding of the surface properties, N₂ physisorption analysis was performed at 77 K. To evaluate the material’s capacity to act as an adsorbent for organic dyes, the adsorption kinetics of organic pollutants were simulated using Crystal Violet as a model molecule, tracking the adsorption trends through UV–vis spectroscopy. In this context, the adsorption capacity of Crystal Violet was determined to exceed 98% within the initial 4 h period.