The main objective of this review is to analyze the equations proposed for expressing the effect of various parameters on porosity formation in aluminum-based alloys. These parameters include alloying elements, solidification rate, grain refining, modification, hydrogen content, as well as the applied pressure on porosity formation in such alloys. They are used to establish as precisely as possible a statistical model to describe the resulting porosity characteristics such as the percentage porosity and pore characteristics, as controlled by the chemical composition of the alloy, modification, grain refining, and the casting conditions. The measured parameters of percentage porosity, maximum pore area, average pore area, maximum pore length, and average pore length, which were obtained from statistical analysis, are discussed, and they are supported using optical micrographs, electron microscopic images of fractured tensile bars, as well as radiography. In addition, an analysis of the statistical data is presented. It should be noted that all alloys described were well degassed and filtered prior to casting.
The present study was performed on A356 alloy [Al-7 wt %Si 0.0.35 wt %Mg]. To that La and Ce were added individually or combined up to 1.5 wt % each. The results show that these rare earth elements affect only the alloy melting temperature with no marked change in the temperature of Al-Si eutectic precipitation. Additionally, rare earth metals have no modification effect up to 1.5 wt %. In addition, La and Ce tend to react with Sr leading to modification degradation. In order to achieve noticeable modification of eutectic Si particles, the concentration of rare earth metals should exceed 1.5 wt %, which simultaneously results in the precipitation of a fairly large volume fraction of insoluble intermetallics. The precipitation of these complex intermetallics is expected to have a negative effect on the alloy performance.
The present study was undertaken to examine the effect of iron, manganese, copper and magnesium on the microstructural characteristics of Al-11%Si-2%Cu-Mg-based alloy referred to as 396 under different working conditions. The results show that strontium (Sr) has high affinity to react with magnesium (Mg), resulting in reduced effectiveness as eutectic silicon modifier or age hardening agent. In addition, Sr alters the sequence of the precipitation of the α-AlFeMnSi phase from post-eutectic to pro-eutectic which would harden the soft α-Aluminum matrix. The mechanism is still under investigation. The interactions between iron (Fe) and Mg and Sr-Mg result in the formation of serval dissolvable intermetallics during the solutionizing treatment such as β-AlFeSi, π-AlFeMgSi and Q-AlMgSiCu phases. The study also emphasizes the role of modification and grain refining as well as intermetallics in porosity formation and hardness of samples aged in the temperature range 155–240 °C.
19 January 2021 in Advances in Materials Science and Engineering
The present study was carried out on three Al‐Si cast alloys viz., 319, 356, and 413 alloys, solidified at 8°C/s. Samples from 319 and 413 alloys were solution heat‐treated at 510°C, whereas samples from 356 alloy were solutionized at 550°C, for up to 1200 h. The results reveal that complete spheroidization of eutectic Si particles in terms of achieving individual spherical particles cannot be achieved in most Al‐Si‐Cu‐Mg alloys even after a solutionizing time of 1200 h which contradicts with the existing theory. Addition of Sr to Cu‐free 356 alloy could lead to complete spheroidization after 1200 h at 550°C if the alloy was solidified at 8°C/s. Besides the dissolution theory of Ostwald, coarsening of Si particles can as well take place by impingement, fusion, and agglomeration. Increasing the Si content makes it difficult to achieve spheroidization, i.e., fragmentation and coarsening. Results obtained from observations of deeply etched samples (3D) contradict those obtained from polished samples (2D).
1 January 2021 in Advances in Materials Science and Engineering
The present study was performed on A356 and B319 alloys in mechanically stirred or degassed condition. Melts were Sr‐modified and grain‐refined. Hydrogen content was varied from less than 0.1 ml/100 g Al to ∼0.4 ml/100 g Al; Fe was increased to 0.8% in B319 alloy. Lanthanum and cerium were added as 99.5% pure metals. Two main techniques were used to investigate porosity formation: fracture surface of tensile or fatigue test bars, or reduced pressure test (RPT) method. Porosity type and shape were examined. The results show that pore size is more influential than small scattered ones from a mechanical point of view. Tensile testing is affected by porosity located at the center of the testing bar, whereas edge porosity is responsible for crack initiation in case of fatigue testing. Intermetallics precipitate in the form of intercepted platelets which restricts the flow of the molten metal, leading to formation of shrinkage cavities. Precipitation of clusters of compounds from the liquid state such as Al2Si2Sr, Mg2Sn, Al3Ti, or added Al2O3particles would as well act as nucleation sites for porosity formation. Most oxides were observed in the form of long branched strings. In some cases, bifilms were also reported in addition to SrO and MgO.
16 May 2019 in International Journal of Metalcasting