Concrete structures in marine environments are subjected to severe conditions that significantly compromise their durability and service life. Exposure to chloride penetration, sulfate attack, and physical erosion accelerates deterioration, leading to extensive maintenance requirements and high associated costs. To address these challenges, significant advancements in surface coatings and inspection technologies have been developed to enhance the longevity of concrete structures. This review examines recent progress in protective surface coatings that mitigate environmental damage and explores state-of-the-art inspection techniques for assessing structural integrity. By providing a comprehensive analysis of innovative materials, coating applications, and non-destructive evaluation methods, this paper aims to equip researchers and industry professionals with effective strategies for preserving concrete infrastructure in marine environments.

Epoxy-based vitrimers represent a paradigm shift in material science, offering an unprecedented combination of mechanical robustness, environmental sustainability, and reconfigurability. These dynamic polymer systems utilize associative dynamic covalent bonds (DCBs) such as transesterification to blend the structural integrity of thermosets with the recyclability and self-healing properties of thermoplastics. This unique combination makes vitrimers ideal candidates for high-performance applications in industries such as civil engineering, where material durability, repairability, and environmental compatibility are critical. Epoxy-based vitrimers, in particular, exhibit exceptional self-healing capabilities, allowing them to autonomously repair microcracks and damage, restoring mechanical properties under appropriate stimuli such as heat or light. Their recyclability further aligns with global sustainability goals by reducing material waste and lifecycle costs. Recent advancements have also integrated bio-based feedstocks and scalable manufacturing methods, enhancing the feasibility of these materials for industrial applications. This review explores the underlying self-healing mechanisms, dynamic recycling processes, and the emerging role of epoxy-based vitrimers in civil engineering. Challenges related to scalability, mechanical optimization, and regulatory acceptance are also discussed, with a focus on their potential to drive sustainable innovation in infrastructure materials.

This study investigated changes in the interfacial properties of epoxy-coated concrete exposed to various conditions, regarding the epoxy type, coating equipment, and exposure environment and period. The measured coating thickness and pull-off bond strength exhibited diverse trends, depending on the exposure period and conditions. In the real sea (RS) environment, the average bond strengths for bisphenol A (BPA) (E1), BPA with zinc powder (E2), and BPA with cresyl glycidyl ether (E3) were 1.26, 1.93, and 1.92 MPa, respectively. The coating method did not significantly affect the measured coating thickness and strength values. The conventional roller (D1) exhibited the highest thickness variation, with a value of 214.45 μm. The RS condition significantly increased the coating thickness (34% to 158%) compared to the tap water (TW) condition. The exposure conditions had little impact on bond strength except for E3, which showed an increased strength (2.71 MPa) over 7–91 days, especially under RS conditions, while E2 remained constant at approximately 1.82 MPa. This study offers insights into factors influencing marine concrete coating performance and discusses limitations and future work.

The evaluation of interfacial bonds between polymeric cementitious composites (PCCs) and concrete is considered as a critical factor to determine structural safety, durability, and service life regarding the repair and strengthening of old concrete structures. Conventional evaluations of interfacial bond strength have primarily relied on destructive testing methods, such as the pull-off and slant shear tests. However, these methods inherently possess fundamental limitations, including localized damage, non-uniform stress distribution, and uncertainty in result interpretation. This review aims to provide a comprehensive overview of existing standards and methods for assessing interfacial bond strength. For this purpose, the evaluation methods and results for the interfacial bond strength between cementitious composites such as PCCs and concrete were systematically reviewed. It further examines the characteristics and sources of error of the representative destructive method (pull-off test), highlighting its inherent limitations. Furthermore, this study conducted an in-depth analysis of a hybrid evaluation strategy combining non-destructive testing (NDT) and artificial intelligence (AI) to overcome the limitations of conventional interfacial bond strength assessment methods and minimize prediction errors. The results demonstrated that the NDT–AI hybrid approach, based on an ANN–BFGS model, achieved the highest accuracy in bond strength prediction and was identified as the optimal method for quantitatively and non-destructively evaluating interfacial bond behavior.

In this study, chlorine-induced corrosion and blister formation on steel pipes (SPs) coated with modified polyethylene powder (MPP) were evaluated through various tests, including chlorine exposure, wet immersion, and temperature gradient experiments. The results confirmed that the extent of corrosion and iron leaching varied with the coating type as expected. In batch leaching tests, no corrosion was observed on modified polyethylene-coated steel pipes (MPCSPs) within a chlorine concentration range of 0 mg/L to 10 mg/L; similarly, there were no significant changes in specimen weight or iron levels. In contrast, the control group with uncoated SPs exhibited significant iron leaching and corrosion, a trend consistent in sequential leaching experiments. SEM analysis after a month of chlorine exposure revealed no significant corrosion on MPCSPs, and SEM-EDX confirmed no major changes in the carbon bond structure, indicating resistance to high chlorine concentrations. Comparative analysis of wet immersion and temperature gradient tests between MPCSP and conventional epoxy-coated SP (ECSP) specimens revealed that MPCSPs did not develop blisters even after 100 days of immersion, whereas ECSPs began showing blisters as early as 50 days. In temperature gradient tests, MPCSPs showed no blisters after 100 days, while ECSPs exhibited severe internal coating layer blisters.