Thermal barrier coating (TBC) is a critical material in the aerospace domain to increase the lifetime of gas turbine components subjected to thermal load. The properties of TBC are strongly related to the growth of thermally grown oxide (TGO) whose main constituent is Al₂O₃. However, the oxidation of Cr and Co can affect the growth of TGO, which is not studied sufficiently. In this paper, high-temperature exposure at 1000 °C was performed to investigate the effect of Cr and Co oxides on TGO growth. The morphology and composition analysis of the interface between the ceramic top coat and the bond coat (TC/BC) were investigated by using scanning electron microscopy (SEM) and the energy dispersion spectrum (EDS). The thermodynamics and kinetics of oxidation were analyzed. The results indicated that the oxidation kinetics basically followed the sub-parabolic law with exposure time. Additionally, the major factor affecting the formation of oxides was the diffusion rate at the initial stage of exposure, then oxides depended on thermodynamics, and the oxidation was influenced by both of them in the last stage. The major elements to be oxidized were different at different stages. Moreover, the replacement reaction of Cr₂O₃ and the phase conversion of Al₂O₃ resulted in thickness variations of the TGO and Al-depleted zone during high-temperature exposure.

Brittle fracture of large forging equipment usually leads to catastrophic consequences. To avoid this kind of accident, the brittle fracture behaviors of a large die holder were studied by simulating the practical application. The die holder is used on the large die forging press, and it is made of 55NiCrMoV7 hot-work tool steel. Detailed investigations including mechanical properties analysis, metallographic observation, fractography, transmission electron microscope (TEM) analysis and selected area electron diffraction (SAED) were conducted. The results reveal that the material generated a large quantity of large size polyhedral M₂₃C₆ (M: Fe and Cr mainly) and elongated M₃C (M: Fe mainly) carbides along the martensitic lath boundaries when the die holder was recurrently tempered and water-cooled at 250 °C during the service. The large size carbides lead to the material embrittlement and impact toughness degradation, and further resulted in the brittle fracture of the die holder. Therefore, the operation specification must be emphasized to avoid the die holder being cooled by using water, which is aimed at accelerating the cooling.

In-situ scanning electron microscopy (SEM) testing based on a small time scale is proposed to integrally investigate the fatigue crack growth behavior and mechanisms, which is different from the widely-used, cycle-based approach due to its small time scale and comprehensive analysis of the effects of microstructure, crack closure and applied loading on crack growth. In the proposed methodology, the behavior of fatigue crack growth at any time within a loading cycle is observed by SEM to investigate the influence of microstructure on crack growth. Images with high resolution are taken to measure the crack tip opening displacement (CTOD), and the correlation between CTOD and the stress intensity factor (SIF) K is studied. A model based on experimental data is used to predict the CTOD variation. The unstable crack growth of aluminum alloy 7050-T7451 is investigated using the proposed method. Results show that this method has great potential in fatigue crack growth mechanism research compared with the traditional cycle-based approach.