This study evaluates radon exhalation rates and assesses the potential radiological risks of external exposure to primordial radionuclides in building materials employed in the Ica region of Peru, particularly those with high uranium content. The radon exhalation rates are currently measured using a combination of a closed chamber and an active monitor. We proposed a novel method that effectively ensured a hermetic seal for the closed chamber and guaranteed that the efficient maintenance of secular equilibrium. The obtained results ranged from below the detection limit (BDL) to a maximum of 52.3 mBq · kg⁻¹h⁻¹. Gamma spectrometry was employed to measure the concentrations of radionuclides by utilizing a 3′ × 3′ NaI detector. The analysis of cement samples revealed a strong positive correlation between the activity concentration of radium and the radon exhalation rate. The activity concentrations for radionuclides varied, with values ranging from BDL to 60.6 mBq · kg⁻¹h⁻¹ for ²²⁶Ra, BDL to 22.3 mBq · kg⁻¹h⁻¹ for ²³²Th, and BDL to 1074 mBq · kg⁻¹h⁻¹ for ⁴⁰K. These findings contribute valuable insight to decision-making processes in the Peruvian construction industry, particularly regarding material safety and radiological risk management.

Mining generates significant amounts of waste that can represent a source of contamination for areas close to the extraction area, generating a negative impact both on the environment and the health of people. This study aims to evaluate the radiological risk derived from exposure to natural radionuclides contained in tailings from Peruvian gold mines and to establish whether the tailings can be used as raw materials in building materials. The mine tailings come from a mining project in the northern highlands of Peru. Radon exhalation was measured using Rad7 in a closed chamber and activity concentration of ²²⁶Ra, ²³²Th, and ⁴⁰K radioisotopes by gamma spectrometry using NaI 3” × 3” detector. Maximum activity concentrations measured for ²²⁶Ra and ²³²Th were 15.38 Bq kg⁻¹ and 11.9 Bq kg⁻¹, respectively; meanwhile, activity concentration for ⁴⁰K ranged from 182.7 Bq kg⁻¹ to 770.8 Bq kg⁻¹. All activity concentrations were below the worldwide average except for ⁴⁰K. The radon exhalation rate varied from 2.8 to 7.2 mBq kg⁻¹ h⁻¹. The gamma index (I_γ), and radiological parameters, including the Radium equivalent activity (Ra_eq), and the external hazard index (H_ex), being below the recommended levels by UNSCEAR, ensure the safe use of these mines tailing to produce a geopolymer cement.