The fabrication of small scale, fixed structure fluidic diodes for simple fluids is quite challenging and has not yet been achieved. Here, we fabricate a moving part-free nanofluidic diode for simple fluids using heterogeneous nanochannels, half of which is hydrophilic and the other half is hydrophobic. It accepts water flows in the forward (from hydrophilic to hydrophobic) direction, while the flows in the backward direction are blocked for pressure drop range $0<\mathrm{\Delta }P<0.63\mathrm{MPa}$. The diode is ensured by a potential energy barrier at the channel entrance on the hydrophobic side due to the molecular interactions between the water and channel surface. As the upstream pressure becomes higher than 0.63 MPa, the fluidic diode turns to be a rectifier, which allows flows in both the forward and backward directions but with different flow rates. At sufficiently high driving pressures, the fluidic system fails in flow rectification, analogous to the breakdown of electronic diodes. The three different flow modes (diode, rectifier, and breakdown) of the fluidic chip and the underlying rectification mechanisms are confirmed by molecular dynamics simulations.

Two-dimensional (2D) materials have enabled promising applications in modern miniaturized devices. However, device operation may lead to substantial temperature rise and thermal stress, resulting in device failure. To address such thermal challenges, the thermal expansion coefficient (TEC) needs to be well understood. Here, we characterize the in-plane TECs of transition metal dichalcogenide (TMD) monolayers and demonstrate superior accuracy using a three-substrate approach. Our measurements confirm the physical range of 2D monolayer TECs and, hence, address the more than two orders of magnitude discrepancy in literature. Moreover, we identify the thermochemical electronegativity difference of compositional elements as a descriptor, enabling the fast estimation of TECs for various TMD monolayers. Our work presents a unified approach and descriptor for the thermal expansion of TMD monolayers, which can serve as a guideline toward the rational design of reliable 2D devices.

We experimentally investigate the Poiseuille flows in nanochannels. It is found that the flow rate undergoes a transition between two linear regimes as the shear rate is varied. The transition indicates that the nonslip boundary condition is valid at low shear rate. When the shear rate is larger than a critical value, slip takes place and the slip length increases linearly with increasing shear rate before approaching a constant value. The results reported in this work can help advance the understanding of flow slip in nanochannels.