The results of studying the effect of particles of few-layer graphene (FLG) synthesized by self-propagating high-temperature synthesis (SHS) on the complex of strength and thermo physical properties of polymer composite products obtained by digital light processing (DLP) 3D printing are presented. It was discovered to achieve an increase in thermophysical and strength parameters of polymers modified by FLG compared with samples made on the unmodified base resin. This result was achieved due to low defectiveness, namely the absence of Stone–Wales defects in the structure of FLG due to the homogeneous distribution of FLG over the volume of the polymer in the form of highly dispersed aggregates. It was possible to increase hardness by 120%, bending strength by 102%, Charpy impact strength by 205%, and thermal conductivity at 25 °C by 572% at concentrations of few-layer graphene of no more than 2 wt. %.
1 January 2023 in Image Journal of Advanced Materials and Technologies
The digital light processing method (DIGITAL LIGHT PROCESSING or DLP) is one of the most affordable 3D printing methods, which allows you to obtain high-precision products, which, however, are inferior in their characteristics to products obtained by other 3D printing methods. Due to their high characteristics, graphene nanostructures can solve this problem by acting as effective modifying additives. However, despite all the promise of this approach, the introduction of graphene nanostructures into actual practice has not yet occurred due to their high cost due to the imperfection of the methods of their synthesis. The paper considers the effectiveness of using few-layer graphene synthesized according to the author's method under conditions of self-propagating high-temperature synthesis from cellulose as a modifying additive to improve the complex strength and thermophysical properties of products from photopolymer resins obtained by DLP 3D printing. It was found that adding few-layer graphene makes it possible to increase Brinell hardness up to 1.8 times, bending strength up to 1.5 times, and thermal conductivity up to 2.2 times compared to the original polymer when using no more than two wt. % few-layer graphene.The data obtained indicate the high efficiency of the synthesized few-layer graphene as a modifying additive in creating products from photopolymer resins using the DLP 3D printing method.
The results of studying the effect of particles of few-layer graphene (FLG) synthesized by self-propagating high-temperature synthesis (SHS) on the complex of strength and thermo physical properties of polymer composite products obtained by DLP 3D printing are presented. It has been discovered to achieve an increase in thermo physical and strength parameters of polymers modified by FLG compared with samples made on the unmodified base resin. This result was achieved due to low defectiveness, namely the absence of Stone-Wales defects in the structure of FLG due to the homogeneous distribution of FLG over the volume of the polymer in the form of highly dispersed aggregates. It was possible to increase hardness by 120 %, bending strength by 102 %, Charpy impact strength by 205 %, and thermal conductivity at 25 °C by 572 % at concentrations of few-layer graphene of no more than 2 wt. %.
Методами индентирования и МКЭ-моделирования исследовано влияние стальной подложки на свойства никелевых пленок толщиной 0,1–9,2 мкм при вдавливании микросферического индентора радиусом 2,5 мкм. Параметр η не постоянен и снижается с толщиной пленки.