The results of studying the effect of particles of few-layer graphene (FLG) synthesized by self-propagating high-temperature synthesis (SHS) on the complex of strength and thermo physical properties of polymer composite products obtained by digital light processing (DLP) 3D printing are presented. It was discovered to achieve an increase in thermophysical and strength parameters of polymers modified by FLG compared with samples made on the unmodified base resin. This result was achieved due to low defectiveness, namely the absence of Stone–Wales defects in the structure of FLG due to the homogeneous distribution of FLG over the volume of the polymer in the form of highly dispersed aggregates. It was possible to increase hardness by 120%, bending strength by 102%, Charpy impact strength by 205%, and thermal conductivity at 25 °C by 572% at concentrations of few-layer graphene of no more than 2 wt. %.
Coatings based on graphene nanostructures represent one of the most promising solutions for protecting metals from corrosion. However, their application remains unprofitable due to the high production costs, which are caused by the imperfections in graphene nanostructures synthesis methods. Therefore, this work utilized few-layer graphene particles synthesized via self-propagating high-temperature synthesis for coating fabrication. The effectiveness of these coatings in protecting metals against corrosion was tested in a salt spray chamber. It was found that the synthesized coatings provide excellent protection for the steel substrate against corrosion, and their effectiveness is significantly higher than that of polymer coatings based on epoxy resin. A hypothesis was proposed to explain the high efficiency of the coatings based on few-layer graphene particles. This is attributed to their low defect density (absence of Stone-Wales defects in their structure) and the presence of multiple layers, which enhances the barrier effect.
Glass fiber Reinforced Polyurethane Foam (RPUF) has found wide application primarily in the aerospace and construction industry due to its outstanding properties. Unlike pure non-reinforced Polyurethane Foam (PUF), it has increased strength characteristics and at the same time retains unique heat and sound insulation properties. The paper considers the features of reinforced polyurethane foam examination in the Microwave (MW) range. It is shown that there is a significant difference in the recorded MW images compared to pure polyurethane foam. This is expressed primarily in the fact that the reinforcing fibers have a dielectric constant that is different from enclosing polyurethane foam, which leads to scattering and reflection of the incident electromagnetic wave on them. Experimental studies have shown that for RPUF, in contrast to PUF, there is an optimal wavelength range in which the contrast of defects against the background of glass fiber reflections is of the greatest value. An experimental comparison of two methods of examination back-scattering and forward-scattering methods was also carried out for RPUF. It is shown that the forward-scattering technology of measurements, if it can be implemented, has certain advantages since allows reducing the contrast of background reflections from the reinforcing fibers.
Coatings based on graphene nanostructures exhibit high thermal conductivity and are capable of effectively protecting materials from the negative effects of ultraviolet radiation. However, due to the imperfections of the methods for synthesizing graphene nanostructures and coatings based on them, the practical application of such coatings remains unprofitable. This paper presents the results of a study of the thermal conductivity and UV-protective properties of coatings synthesized by chemically crosslinking few-layer graphene particles on ABS plastic substrates. Few-layer graphene particles synthesized under self-propagating high-temperature synthesis conditions were used as the starting material for the coating synthesis. The synthesized coatings were found to have a thermal conductivity of 244 W/(m × K) and are capable of effectively protecting ABS plastic substrates from the negative effects of UV radiation, allowing the products to maintain their required strength characteristics. The high productivity of the method for synthesizing few-layer graphene (up to 10 kg/month at the laboratory production level), as well as the simplicity of the method for synthesizing coatings based on it, allows us to hope for the cost-effectiveness of such coatings.
1 September 2014 in Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques
The impact of microwave radiation and heat treatment on the structure, morphology, and physical and mechanical properties of diamond-like coatings is studied; recrystallization of the coating structure is revealed. It is ascertained that microwave irradiation of diamond-like coatings changes their physical and mechanical properties.
The results of studying the effect of particles of few-layer graphene (FLG) synthesized by self-propagating high-temperature synthesis (SHS) on the complex of strength and thermo physical properties of polymer composite products obtained by DLP 3D printing are presented. It has been discovered to achieve an increase in thermo physical and strength parameters of polymers modified by FLG compared with samples made on the unmodified base resin. This result was achieved due to low defectiveness, namely the absence of Stone-Wales defects in the structure of FLG due to the homogeneous distribution of FLG over the volume of the polymer in the form of highly dispersed aggregates. It was possible to increase hardness by 120 %, bending strength by 102 %, Charpy impact strength by 205 %, and thermal conductivity at 25 °C by 572 % at concentrations of few-layer graphene of no more than 2 wt. %.