Thermoelectric materials have the ability to transform thermal energy into electrical energy and vice versa. For an extended period of time, only inorganic materials have been considered for thermoelectric research and application, but recent advances in the field of organic semiconductors established the basis for organic thermoelectrics research. Pristine organic semiconductors often face the problem of undesirable suboptimal transport properties and, therefore, recent approaches have focused on combining different materials, where both organic–organic and organic–inorganic hybrid systems have led to improved efficiency in organic thermoelectrics. This review aims to provide a general overview on the recent advances for organic-based thermoelectrics with an emphasis on the most thoroughly investigated material classes and the approaches employed to control their thermoelectric transport properties.

Cation doping is an effective strategy for improving the cyclability of layered oxide cathode materials through suppression of phase transitions in the high voltage region. In this study, Mg and Sc are chosen as dopants in P2‐Na_0.67Ni_0.33Mn_0.67O₂, and both have found to positively impact the cycling stability, but influence the high voltage regime in different ways. Through a combination of synchrotron‐based methods and theoretical calculations it is shown that it is more than just suppression of the P2 to O2 phase transition that is critical for promoting the favorable properties, and that the interplay between Ni and O activity is also a critical aspect that dictates the performance. With Mg doping, the Ni activity can be enhanced while simultaneously suppressing the O activity. This is surprising because it is in contrast to what has been reported in other Mn‐based layered oxides where Mg is known to trigger oxygen redox. This contradiction is addressed by proposing a competing mechanism between Ni and Mg that impacts differences in O activity in Na_0.67Mg_xNi_0.33‐xMn_0.67O₂ (x < 0 < 0.33). These findings provide a new direction in understanding the effects of cation doping on the electrochemical behavior of layered oxides.