Several series of six-cell photovoltaic test-modules—intact and with deliberately generated failures (micro-cracks, cell cracks, glass breakage and connection defects)—were artificially and naturally aged. They were exposed to various stress conditions (temperature, humidity and irradiation) in different climate chambers in order to identify (i) the stress-induced effects; (ii) the potential propagation of the failures and (iii) their influence on the performance. For comparison, one set of test-modules was also aged in an outdoor test site. All photovoltaic (PV) modules were thoroughly electrically characterized by electroluminescence and performance measurements before and after the accelerated ageing and the outdoor test. In addition, the formation of fluorescence effects in the encapsulation of the test modules in the course of the accelerated ageing tests was followed over time using UV-fluorescence imaging measurements. It was found that the performance of PV test modules with mechanical module failures was rather unaffected upon storage under various stress conditions. However, numerous micro-cracks led to a higher rate of degradation. The polymeric encapsulate of the PV modules showed the build-up of distinctive fluorescence effects with increasing lifetime as the encapsulant material degraded under the influence of climatic stress factors (mainly irradiation by sunlight and elevated temperature) by forming fluorophores. The induction period for the fluorescence effects of the polymeric encapsulant to be detectable was ~1 year of outdoor weathering (in middle Europe) and 300 h of artificial irradiation (with 1000 W/m2 artificial sunlight 300–2500 nm). In the presence of irradiation, oxygen—which permeated into the module through the polymeric backsheet—bleached the fluorescence of the encapsulant top layer between the cells, above cell cracks and micro-cracks. Thus, UV-F imaging is a perfect tool for on-site detection of module failures connected with a mechanical rupture of solar cells.
8 June 2015 in International Journal of Photoenergy
For a complete quality control of different thin film module technologies (a-Si, CdTe, and CIS) a combination of fast and nondestructive methods was investigated. Camera-based measurements, such as electroluminescence (EL), photoluminescence (PL), and infrared (IR) technologies, offer excellent possibilities for determining production failures or defects in solar modules which cannot be detected by means of standard power measurements. These types of optical measurement provide high resolution images with a two-dimensional distribution of the characteristic features of PV modules. This paper focuses on quality control and characterization using EL, PL, and IR imaging with conventional cameras and an alternative excitation source for the PL-setup.
The outdoor performance monitoring of perovskite modules over 16 weeks is reported. Two different types of active perovskite layers were studied: one type contained formamidinium chloride (FACl) halide additives and the other contained no additives with the main purpose to investigate performance trends during the outdoor exposure of those type of devices. Long-term side-by-side outdoor testing of devices with and without halide additives was not implemented in the past and merits investigation in order to determine the impact of additives on perovskite performance and stability. Although the two types of modules displayed similar initial outdoor performance characteristics, their outdoor performance evolution differed. Different degradation rates between the modules with and without additives were obtained just after field installation. In particular, the modules with additives exhibited higher performance degradation under open-circuit loading conditions between current-voltage (IV) scans. Long-term monitoring of both modules recorded a reduction of the efficiency over the course of the day with subsequent recovery overnight and in many cases during the day. The relative values of performance degradation and overnight recovery were calculated over the timespan of outdoor testing and indicated dominant normalized diurnal performance degradation in one type of modules (without FACl additives) in the range between 15–20% and in the other type of modules (with additives) 5–10%. The dominant normalized performance recovery values found were 25–30% and 5–10%, respectively. Finally, dark lock-in thermography (DLIT) and Raman studies were performed on the exposed devices and revealed differences in hotspot evolution and vibrational modes between the different types of module.
As renewable energies need to be extended massively, new concepts are necessary to prevent land conflicts with other uses. Such concepts should have a high generality to offer a swift expansion of renewables anywhere. Within the project, the Photovoltaic Road Roofing Concept (PV-SÜD), a concept for the roofing of roadways with solar panels, was investigated. Its effects on the road infrastructure were analyzed, and a demonstrator was built. The technical boundary conditions and requirements resulting from the specific application type were determined regarding the photovoltaic technology, the possible energy generation, and the supporting structure. The study was completed for a technical solution of 10 m length, 17 m width, and 6.8 m height, with the option of a pent roof (highways running east–west) or gable roofs (highways running north–south). The main target aim was to investigate the potential for widespread use at any site, in contrast to previous studies which mainly aimed at a singular site or demonstrator project. The final solution can support a 38.5 kWp photovoltaic system with a specific annual yield of between 37.5 MWh and 44.0 MWh. The yield variation in sites in Austria and Germany was 14.7% and 17.9%, respectively. One demonstrator roofing was realized as a steel-frame construction with active glass–glass photovoltaic technology at a highway in Hegau (GE).
Organic–inorganic hybrid metal halide perovskites are poised to revolutionize the next generation of photovoltaics with their exceptional optoelectronic properties and compatibility with low-cost and large-scale fabrication methods. Since perovskite tends to degrade over short time intervals due to various parameters (oxygen, humidity, light, and temperature), advanced characterization methods are needed to understand their degradation mechanisms. In this context, investigation of the electrical and optoelectronic properties of several perovskite mini-modules was performed by means of photo- and electroluminescence imaging as well as Dark Lock-In Thermography methods. Current–voltage curves at periodic time intervals and External Quantum Efficiency measurements were implemented alongside other measurements to reveal correlations between the electrical and radiative properties of the solar cells. The different imaging techniques used in this study reveal the changes in radiative emission processes and how those are correlated with performance. Alongside the indoor optoelectronic characterization of perovskite reference samples, the outdoor monitoring of two perovskite modules of the same structure for 23 weeks is reported. Significant performance degradation is presented outdoors from the first week of testing for both samples under test. The evolution of the major electrical characteristics of the mini-modules and the diurnal changes were studied in detail. Finally, dark storage recovery studies after outdoor exposure were implemented to investigate changes in the major electrical parameters.