Detecting insulation performance through testing the Raman spectroscopy of transformer oil is noninvasive and shows great promise in on-site diagnosis. The information, stored in spectra, that may reflect aging states of insulation aims to be effectively unfolded and provides decision support as well. In this article, a transformation method based on intrinsic product arithmetic is used to transform the 1-D Raman spectral data into 2-D image data. With the help of CNN based on the dimensionality expanding method, diagnosis of oil-paper insulation with different aging states based on the Raman spectroscopy was realized. The network-based oil-paper insulation aging diagnosis model has an accuracy of 95% in ten aging categories of 60 test samples and 100% in four aging categories. The result shows the trained CNN was able to identify the differences of transformer oil samples at each aging stage through visualized Raman spectral image. This method provides a more accurate determination method for diagnosing oil-immersed transformers' aging conditions; it also develops an available method for a more detailed evaluation of insulation aging levels.

The detection of furfural in transformer oil through surface enhanced Raman spectroscopy (SERS) is one of the most promising online monitoring techniques in the process of transformer aging. In this work, the Raman of individual furfural molecules and SERS of furfural-M_x (M = Ag, Au, Cu) complexes are investigated through density functional theory (DFT). In the Raman spectrum of individual furfural molecules, the vibration mode of each Raman peak is figured out, and the deviation from experimental data is analyzed by surface charge distribution. In the SERS of furfural-M_x complexes, the influence of atom number and species on SERS chemical enhancement factors (EFs) are studied, and are further analyzed by charge transfer effect. Our studies strengthen the understanding of charge transfer effect in the SERS of furfural molecules, which is important in the online monitoring of the transformer aging process through SERS.

Accurate detection of dissolved aging features in transformer oil is the key to judging the aging degree of oil-paper insulation. In this work, in order to realize in situ detection of furfural dissolved in transformer oil, silver nanoparticles were self-assembled on the surface of gold film with P-aminophenylthiophenol (PATP) as a coupling agent. Rhodamine-6G (R6G) was used as the probe molecule to test the enhancement effect. By optimizing the molecular concentration, molecular deposition time, and silver sol deposition time of PATP, the nanoparticles were made more uniform and compact, and an enhanced substrate with rich hot spots was obtained. The optimum substrate was developed, and surface-enhanced Raman spectroscopy (SERS) detection of trace furfural dissolved in transformer oil was realized. The results showed that the substrate prepared under the conditions of 0.1 mol/L PATP, 5 h deposition in PATP and 12 h immersion in silver sol, had the best reinforcement effect (that is, uniform and compact particle arrangement and no particle clusters). By use of this substrate, the minimum detectable concentration of furfural in transformer oil was about 1.06 mg/L, which provides a new method for fast and nondestructive detection of transformer aging diagnosis.

The Raman detection of trace substances (∼26 ppb) in complex mineral oils based on microdroplet extraction was demonstrated.

Low-frequency sound absorption metamaterials often face a trade-off among ventilation performance, noise reduction effectiveness, and bandwidth. Maze structures, utilizing deep subwavelength designs, can effectively control low-frequency sound waves and achieve multifaceted performance optimization. This paper presents a metamaterial based on a double-helix space-curved (DSC) structure that maintains excellent ventilation performance (exceeding 98%) while demonstrating superior acoustic properties. A single-peak absorption sample achieved a high sound absorption efficiency of 0.832 at 384 Hz, while a broadband sample achieved over 80% sound absorption within the 390 to 431 Hz range. Under both ventilated and non-ventilated conditions, the acoustic transmission performance remained essentially unchanged, offering new insights for the development of ventilation-based noise reduction technologies.