Cobalt–chromium–molybdenum (Co-Cr-Mo) alloy is a material recommended for biomedical implants; however, to be suitable for this application, it should have good tribological properties, which are related to grain size. This paper investigates the tribological behaviour of a Co-Cr-Mo alloy produced using investment casting, together with electromagnetic stirring, to reduce its grain size. The samples were subjected to wear and scratch tests in simulated body fluid (Ringer’s lactate solution). Since a reduction in grain size can influence the behaviour of the material, in terms of resistance and tribological response, four samples with different grain sizes were produced for use in our investigation of the behaviour of the alloy, in which we considered the friction coefficient, wear, and scratch resistance. The experiments were performed using a tribometer, with mean values for the friction coefficient, normal load, and tangential force acquired and recorded by the software. Spheres of Ti-6Al-4V and 316L steel were used as counterface materials. In addition, to elucidate the influence of grain size on the mechanical properties of the alloy, observations were conducted via scanning electron microscopy (SEM) with electron backscatter diffraction (EBSD). The results showed changes in the structure, with a reduction in grain size from 5.51 to 0.79 mm. Using both spheres, the best results for the friction coefficient and wear volume corresponded to the sample with the smallest grain size of 0.79 mm. The friction coefficients obtained were 0.37 and 0.45, using the Ti-6Al-4V and 316L spheres, respectively. These results confirm that the best surface finish for Co-Cr-Mo alloy used as a biomedical implant is one with a smaller grain size, since this results in a lower friction coefficient and low wear.
The aim of this work was to study the stability and morphological properties of polystyrene latex containing kaolinite as a filler during the process of synthesis of nanocomposites viaemulsion polymerization. Nanocomposites with 1, 3, and 5 wt% of kaolinite were prepared. Latexes with 1 to 3 wt% of kaolinite were stable during the polymerization reaction. Hydrodynamic diameters of 93.68 and 82.11 nm were found for latexes with 1 and 3 wt% of kaolinite, respectively. The quantities of 1 to 3 wt% of kaolinite added during the reaction did not influence the reaction conversion curves or the number of particles. X-ray diffraction (XRD) and unconventional techniques of scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) showed the presence of exfoliated and intercalated structures of the kaolinite.
1 April 2023 in Journal of Research Updates in Polymer Science
The application of lignocellulosic fibers as reinforcements in composite materials has found increasing use in recent years, due to the attractive characteristics of natural fibers such as their low cost, high specific modulus, biodegradability, abundance and with many technical qualities. Natural fiber hybrid composites are very frequently used in automotive aerospace and other industries. In this work, numerical and experimental analysis is carried out to compare curauá, jute and sisal fibers in epoxy composites for use in industry. The most appropriate hybridization effect by establishing the amounts of each fiber on the mechanical properties was considered. Finite Element Models were designed and validated through mechanical tests. The number of Finite Element models and specimens performed was determined through the design of experiments using the Taguchi Method and then the results were statistically validated. Higher strength was obtained in composites made with curauá fiber, followed by jute and sisal fibers. Such behavior was achieved by FEM and experimental tests, revealing an increase in tensile strength by increasing the amount of fibers up to 35% in total. Higher strength was achieved when the composite was made with curauá (20 wt.%), jute (10 wt.%) and sisal (5 wt.%) fibers. The results show a good agreement between the FEM and the experimental tests. Furthermore, the results of the present study were compared with those obtained previously mentioned in the open literature.
This study investigates the tribocorrosion performance of a cast Co-Cr-Mo alloy prepared using casting and electromagnetic stirring (EMS) at specific frequencies. The tribocorrosion behaviour of the alloy was evaluated when exposed to Ringer’s lactate solution to optimize the EMS parameters and improve its properties. The research focuses on biomedical implant applications and explores how EMS affects alloy wear and corrosion resistance. As did the friction coefficient and wear volume, the wear rate of samples produced with EMS frequencies of 75 Hz and 150 Hz decreased. These improvements are attributed to the ability of EMS to refine grain size and homogenize the microstructure, thereby increasing the resistance to tribocorrosion. Techniques such as scanning electron microscopy (SEM) and profilometry were used for surface and wear analysis, while mechanical properties were evaluated through instrumented indentation tests. The findings confirm that EMS improves the alloy’s durability and tribocorrosion resistance, making it highly suitable for demanding biomedical applications such as joint replacements. This highlights the importance of advanced manufacturing techniques in optimizing biomedical alloys for simulated body conditions.
An interest in the search for materials with reduced thicknesses, high mechanical resistance and low density has been increasing by the industry. The addition of niobium in micro-alloyed steels in the automotive industry is an alternative for obtaining light and resistant materials. The objective of this work was to verify the influence of the niobium and the heat treatment of normalizing in the microstructure and hardness of the steel SAE 8620. Also the behavior of the cementation in the steel was studied. It was verified that the removal of the normalization heat treatment did not affect the microstructure and the hardness of the steel with the niobium in relation to the steel without niobium and normalization. The cemented layer for the steel with niobium presented a greater microhardness to the depth in relation to steel without niobium.