Atmospheric pressure plasma jets (APPJs) can be generated in capillary tubes flowing with pure helium and with admixtures of oxygen into the pure helium. The jet exiting the tube can be used for a variety of applications through surface interaction. In this study, a two-dimensional axi-symmetric model has been developed to provide insight into the evolution of capillary helium plasma jets with and without oxygen admixtures and their interaction with a dielectric surface placed normal to the jet axis. The model considers the gas mixing of helium and ambient air and the analytical chemistry between helium, nitrogen and oxygen species. Experiments were performed in conditions similar to those of the simulations in order to get qualitative agreement between them. The numerical and experimental results show that the evolution of the helium plasma jet is strongly affected by the introduction of oxygen admixtures. In particular, it was observed that the addition of oxygen admixtures in the helium gas promotes plasma bullet propagation on the axis of symmetry of the tube (in contrast to off-axis propagation for the pure helium plasma jet). On the other hand, the presence of the dielectric surface (a slab placed in front of the tube exit) forces the plasma bullet to spread radially. Furthermore, the plasma bullet speed decreases when the helium plasma jet is operated in the presence of oxygen admixtures. The numerical results also showed that He/O 2 plasma jets induced much higher electric fields on the dielectric surface in comparison to the pure helium plasma jet.
Non-thermal plasma (NTP) is a novel and promising technique in the agricultural field that has the potential to improve vegetal material by modulating the expression of various genes involved in seed germination, plant immune response to abiotic stress, resistance to pathogens, and growth. Seeds are most frequently treated, in order to improve their ability to growth and evolve, but the whole plant can also be treated for a fast adaptive response to stress factors (heat, cold, pathogens). This review focuses mainly on the application of NTP on seeds. Non-thermal plasma treated seeds present both external and internal changes. The external ones include the alterations of seed coat to improve hydrophilicity and the internal ones refer to interfere with cellular processes that are later visible in metabolic and plant biology modifications. The usage of plasma aims to decrease the usage of fertilizers and pesticides in order to reduce the negative impact on natural ecosystem and to reduce the costs of production.
Atmospheric-pressure plasma (APP) has advantages for enhancing the adhesion of polymers and has to provide uniform, efficient treatment, which also limits the recovery effect of treated surfaces. This study investigates the effects of APP treatment on polymers that have no oxygen bonded in their structure and varying crystallinity, aiming to assess the maximum level of modification and the post-treatment stability of non-polar polymers based on their initial structure parameters, including the crystalline–amorphous structure. An APP reactor simulating continuous processing operating in air is employed, and the polymers are analyzed using contact angle measurement, XPS, AFM, and XRD. APP treatment significantly enhances the hydrophilic character of the polymers, with semicrystalline polymers exhibiting adhesion work values of approximately 105 mJ/m2 and 110 mJ/m2 for 0.5 s and 1.0 s exposure, respectively, while amorphous polymers reach approximately 128 mJ/m2. The maximum average oxygen uptake is around 30%. Short treatment times induce the roughening of the semicrystalline polymer surfaces, while the amorphous polymer surfaces become smoother. The polymers exhibit a limit to their modification level, with 0.5 s exposure being optimal for significant surface property changes. The treated surfaces remain remarkably stable, with the contact angle only reverting by a few degrees toward that of the untreated state.