In this paper, an overview of the recent applications of pulsed infrared thermography is presented. Pulsed infrared thermography, which provides stratigraphic information by analyzing the heat diffusion process within the sample after a thermal perturbation, is applied to the investigation of different kinds of cultural heritage artefacts. In particular, it is used to analyze repairs, decorative elements, and casting faults on bronzes, to detect texts hidden or damaged in ancient books/documents, and to characterize paint decorations. Moreover, the integration of pulsed infrared thermography and three-dimensional shape recording methods is proposed in order to provide a three-dimensional representation of the thermographic results. Finally, it is shown how the obtained thermographic results may be crucial from the historical and artistic points of view for understanding the modus operandi of a specific artist and/or of a workshop and for reconstructing the manufacturing process of the analyzed artefacts.
A novel type of graphene-like quantum dots, synthesized by oxidation and cage-opening of C60 buckminsterfullerene, has been studied as a fluorescent and absorptive probe for heavy-metal ions. The lattice structure of such unfolded fullerene quantum dots (UFQDs) is distinct from that of graphene since it includes both carbon hexagons and pentagons. The basic optical properties, however, are similar to those of regular graphene oxide quantum dots. On the other hand, UFQDs behave quite differently in the presence of heavy-metal ions, in that multiple sensitivity to Cu2+, Pb2+ and As(III) was observed through comparable quenching of the fluorescent emission and different variations of the transmittance spectrum. By dynamic light scattering measurements and transmission electron microscope (TEM) images we confirmed, for the first time in metal sensing, that this response is due to multiple complexation and subsequent aggregation of UFQDs. Nonetheless, the explanation of the distinct behaviour of transmittance in the presence of As(III) and the formation of precipitate with Pb2+ require further studies. These differences, however, also make it possible to discriminate between the three metal ions in view of the implementation of a selective multiple sensor.
Over the recent period, there has been an increasing interest in the use of pulsed infrared thermography (PT) for the non-destructive evaluation of Cultural Heritage (CH). Unlike other techniques that are commonly employed in the same field, PT enables the depth-resolved detection of different kinds of subsurface features, thus providing helpful information for both scholars and restorers. Due to this reason, several research activities are currently underway to further improve the PT effectiveness. In this manuscript, the specific use of PT for the analysis of three different types of CH, namely documentary materials, panel paintings–marquetery, and mosaics, will be reviewed. In the latter case, i.e., mosaics, passive thermography combined with ground penetrating radar (GPR) and digital microscopy (DM) have also been deepened, considering their suitability in the open field. Such items have been selected because they are characterized by quite distinct physical and structural properties and, therefore, different PT (and, in some cases, verification) approaches have been employed for their investigations.