Alloys with an equal balance of ferrite and austenite provide super duplex stainless steel (DSS) with enhanced strength and corrosion resistance. This study utilized mechanical alloying to produce nanostructured super duplex stainless steel powders for the identification of methylene blue dye in wastewater. High-energy particle grinding was employed to create the SAF-2507 DSS powders. To electrochemically oxidize methylene blue dye in wastewater, a modified carbon paste electrode (DSS-MCPE) was developed. Methylene blue, a water-soluble cationic colorant extensively used in the paper, pulp, and textile industries, poses a threat to human health and water supplies when improperly disposed of. DSS-MCPE demonstrated a significant current response, indicating its capability to detect methylene blue dye in a pH range of 6–8. The experiment revealed that 2 mg of DSS-MCPE produced a maximum current response of 72.22 μA, facilitating the effective electrooxidation of methylene blue dye in wastewater. Furthermore, the investigation demonstrated that the active surface area of the 2 mg of DSS-MCPE (0.478 cm2) was greater than that of the bare carbon paste electrode (BCPE) (0.054 cm2). The increased active surface area was correlated with an enhanced current response. The strong interaction between methylene blue molecules at the interface of the produced 2 mg of DSS-MCPE contributed to the observed increase in anodic current across methylene blue concentrations ranging from 0.1 to 0.6 mM.

SAF-2507 super duplex stainless steel powders (SDSS) were prepared using a high-energy planetary ball milling process. The X-ray diffraction (XRD) shows peak broadening after 20 h of ball milling and revealed a phase transformation resulting in a two-phase alloy mixture containing nearly equal amounts of ferrite (α) and austenite (γ). After 20 h of ball milling the particle size was reduced to ~201 nm. Scanning electron microscope (SEM) micrographs showed small-size irregular grains with an average particle size ranging from 5–7 µm. The high-resolution transmission microscope (HRTEM) analysis confirmed the presence of nanocrystalline particles with sizes ranging from 10 to 50 nm. The presence of ferrite phase is visible in the corresponding diffraction pattern as well. In this paper, we have discussed the electrochemical sensor application of mechanically alloyed nano-structured duplex stainless steel powders. The fabricated 4 mg duplex stainless steel modified carbon paste electrode (SDSS-MCPE) has shown excellent current sensitivity in comparison with 2, 6, 8, and 10 mg SDSS-MCPEs during the detection of ascorbic acid (AA) in a phosphate buffer solution with a pH of 6.8. The calculated electrode active surface area of SDSS-MCPE was found to be almost two times larger than the surface area of the bare carbon paste electrode (BCPE). The limit of detection (LD) and limit of quantification (LQ) were found to be 0.206 × 10⁻⁸ M and 0.688 × 10⁻⁸ M, respectively, for the fabricated 4 mg SDSS-MCPE.

Metal organic frameworks when subjected to varying temperatures and frequencies. The analysis indicate the presence of guest molecules enhance the dielectric constant. The dielectric constant increase to a limit with the rise in temperature but it reduces gradually. The increase in frequencies enhance the peaks of permittivity towards higher temperatures. Shortening of ion diffusion also enhances the capacitance and a better contact between the electrode and active substance increases the electrochemical performance. Luminescence, the color depends on particle size, the structure and intermolecular packing of atoms in material. This paper gives an overview of MOFs studied based on their dielectric, super-capacitive and photo-luminescence when subjected to varying temperatures and frequencies.

Any mechanical device that involves relative motion between two things, such as the piston cylinder in an IC engine, ball mill units in cement plants and therma